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Meeting MS&T25: Materials Science & Technology
Symposium Advancements in Molten Salt/Metal Technology in Energy Applications: From Atoms to Plants
Presentation Title A Computational Approach to Investigate the Role of Impurities on Corrosion Behavior in Molten Salt Reactors
Author(s) Soumya Bandyopadhyay, Michael R. Tonks
On-Site Speaker (Planned) Soumya Bandyopadhyay
Abstract Scope The corrosion of structural alloys by molten salt presents a formidable challenge in the context of molten salt reactors. To address this, we have developed a mesoscale model to comprehend and potentially mitigate such corrosion phenomena. Our electrochemical corrosion model leverages the phase field method implemented within the MOOSE framework to predict the complex diffusional interplay of alloying elements into the salt, with a particular focus on rapid diffusion along grain boundaries within the alloy system. We have applied this model to investigate fluctuating impurity concentrations, emphasizing the tracking of HF concentration through static salt experiments. Furthermore, we have also explored the impact of water vapor on the corrosion process.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Computational Approach to Investigate the Role of Impurities on Corrosion Behavior in Molten Salt Reactors
Accurate Free Energy Simulations in Molten Salts with Machine Learning Potentials and High-Level Quantum Chemical Methods
Beyond proof of concept: the role of lab scale pilots in parallel to commercial operations
Development of a Thermal Conductivity Model for Molten Salts Based on the Pair Distribution Function
Electrochemical behavior of oxygen-evolving precious metal anodes in molten LiCl-Li2O electrolyte
EuCl3 mediated corrosion of Ni and Ni-20Cr Model Alloy in LiCl-KCl molten salt
Experimental calorimetry of heat capacity and mixing enthalpy of molten chloride salts
Fuel Salt Synthesis for the Molten Chloride Reactor Experiment: Scale-up, Operations, and Production Update
Laser-Spectroscopy Testbed for Impurity Monitoring in High-Temperature Reactors
Molten Salt Properties Capabilities at ORNL
Novel Al/Ti-Modified Ni-Mo-W-Cr Alloys for High Temperature Structural Applications in Molten Chloride Fast Reactors
Radiation-induced iodine chemistry in high-temperature molten salts
Separation of fission products from high-level waste salt via melt-crystallization
Synchrotron-Based X-ray Spectroscopy of Molten Salts
Testing Reference Electrodes in FLiNaZr Molten Salt
The Effect of Irradiation on the Densities of Chloride-Bearing Molten Salts
Towards the development of an inert anode for reprocessing of used nuclear fuel

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