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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Next Generation Electrometallurgical Technologies for Metal Extraction, Refining, and Recycling
Presentation Title Molten Salt Electrolysis for Iron Production: Progress Toward Decarbonized Ironmaking
Author(s) Hojong Kim
On-Site Speaker (Planned) Hojong Kim
Abstract Scope Decarbonizing ironmaking requires transformative alternatives to conventional carbothermal reduction. This work investigates molten salt electrolysis as a pathway for direct iron production from iron oxides at intermediate temperatures, offering a promising approach to electrified ironmaking while overcoming challenges associated with both aqueous and high-temperature molten oxide electrolysis. Molten chloride-based electrolytes were developed to enable electrochemical reduction of iron oxides at the cathode and oxygen evolution at the anode. The study focused on understanding electrolyte chemistry, electrode behavior, and materials stability under conditions relevant to sustained iron production. Candidate anode materials were evaluated to identify approaches for improved durability and scalability, and the process was extended from reagent-grade feedstocks to commercial iron ore materials. Ongoing studies are examining the effects of ore impurities on electrochemical performance and material stability. These results demonstrate the technical feasibility of intermediate-temperature molten salt electrolysis and highlight its potential as a scalable route toward low-carbon ironmaking.
Proceedings Inclusion? Planned:
Keywords Electrometallurgy, Iron and Steel, Process Technology

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Rotating Porous Cathode Electrolytic Cell for Quasi-Continuous, Sustainable Iron Powder Production from Copper Smelting Dust
Carbon Emissions Assessment of Steelmaking Routes for 40Cr Steel
Closed-Loop Electrochemical Extraction and Recovery of Critical Minerals Using Low-Cost Open-Source Ion Exchange Membranes
Decarbonizing metal extraction through molten salt electrolysis with non consumable anodes
Electrometallurgy for Lithium Extraction and Processing
Electrons as Reductants: Transforming Metal Production through Electrometallurgy
Engineering Transition Metal Oxide Electrode for Direct Lithium Extraction from Aqueous Brines
Evidence of Silicon Production from Fluxed End-of-Life Photovoltaic Glass via Molten Oxide Electrolysis
High-Temperature Molten Salt Electrolysis for Sustainable Small-Molecule Chemical Synthesis
Liquid-Metal Bipolar Membrane for Electrochemical Recovery of Critical Metals in Molten Salts
Molten Salt Electrolysis for Iron Production: Progress Toward Decarbonized Ironmaking
Nordic Salt Cycle – Scaling a Molten Salt Process for Critical Mineral Recovery to Pilot
Recovery of Valuable Metals From Secondary Resources Using Molten Oxide Electrolysis
Thermodynamic and Experimental Investigation of In-Furnace Recycling of Electric Arc Furnace Dust
Three-Layer Electrorefining of Liquid Zn and Pb Held on/in Porous Holding Materials in Molten Chlorides

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