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Meeting MS&T25: Materials Science & Technology
Symposium TMS Frontiers of Materials Award Symposium: Harnessing Charged and Chemical Defects for Exceptional Structural and Functional Properties
Presentation Title Understanding recombination-enhanced dislocation processes for semiconductor optoelectronics
Author(s) Kunal Mukherjee
On-Site Speaker (Planned) Kunal Mukherjee
Abstract Scope Emerging applications in integrated photonics require the integration of III-V semiconductor lasers and detectors directly onto silicon substrates. However, lattice and thermal expansion mismatch between these materials introduce a high density of dislocations in the III-V layers, degrading device performance. We grow GaAs-on-Si thin films and investigate the behavior of dislocations under device operation. We show that carrier injection drives dislocation glide and climb even at room temperature, ultimately leading to device failure. This motion is fueled by nonradiative recombination of the injected electrons and holes. By alloying GaAs with indium and incorporating InAs quantum dots, we harden the lattice and reduce nonradiative recombination, effectively mitigating dislocation motion. These findings advance our understanding of recombination-enhanced dislocation motion and open pathways to reliable III-V optoelectronics on silicon.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Atomistic Roughening of μm-Long Dislocation Lines under Electric Fields
Charged Dislocations, Electroplasticity and Photoplasticity in Ionic Crystals and Semiconductors
Concentration Gradients of Ionic Point Defects in Functional Oxides
Defect chemistry regulated dislocation plasticity across the length scale in SrTiO3
Dislocation induced plasticity in ceramics
Dynamics of Dislocations and Grain Boundaries in Oxides
Electric Fields Effects on Microstructural Evolution
Electroplasticity of metallic nanomaterials under extreme electrical field
Exploring Photoplastic and Electroplastic Phenomena in ZnS by Misfit Dislocation Imaging
Investigation of grain boundary segregation in ceramic materials using advanced electron microscopy
Nanoscale evaluation of light illumination effect on dislocation behavior in III-V group semiconductors by photoindentation
On the Embrittlement of Grain Boundaries in CdTe from CdCl2 Passivation
Phenomena in Metals and Alloys Controlled at the Single Defect Level
Tailoring Defects in Semiconductors: From Highly Mismatched Alloys to Polytype Heterostructures
The origin of photo plasticity in II-V compounds
Understanding recombination-enhanced dislocation processes for semiconductor optoelectronics
Understanding Self-Catalyzed Growth Kinetics of III-V Semiconductors by Modeling Solid–Melt Interfaces

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