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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Circular Metallurgy: Design, Technology, Application
Presentation Title Alkali-Based Hydrogen Reduction of Molybdenite: A Review of Process and Research Progress
Author(s) Chen Meng, Xinming Zeng, Yan Liu, Ting-an Zhang
On-Site Speaker (Planned) Chen Meng
Abstract Scope Molybdenite (MoS2) is the primary feedstock for molybdenum production, yet conventional smelting routes suffer from lengthy flowsheets, severe pollution, and low resource efficiency, falling short of low-carbon metallurgy requirements. The alkali-based hydrogen reduction process offers a promising alternative. Using alkali compounds such as CaCO3 and Na2CO3 as both sulfur-fixing agents and catalysts, this method enables direct MoS2 reduction in a H2 atmosphere while immobilizing sulfur as solid sulfides, thereby eliminating SO2 emissions at source and simplifying the process flow. This review systematically surveys existing extraction technologies—including oxidative roasting–ammonia leaching, improved roasting, full hydrometallurgical methods, vacuum thermal decomposition, and reductive roasting—with a critical assessment of their respective merits and drawbacks. Special attention is given to the alkali-based hydrogen reduction route, its reaction mechanisms, and its industrial application prospects.
Proceedings Inclusion? Undecided
Keywords Pyrometallurgy, Extraction and Processing, Environmental Effects

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Thermodynamics-Guided Computational Framework for the Sustainable Design of Secondary Aluminium Alloys for Packaging Applications
Additive Manufacturing of Metals: From Complex Alloys to Simple Alloys
Advances in scale effect and adaptive scale-up theory of liquid-solid two-phase reactors
Alkali-Based Hydrogen Reduction of Molybdenite: A Review of Process and Research Progress
Circular hydrometallurgy: from direct electrolysis of iron oxides to energy conversion and storage material synthesis and recycling
Controlling Iron-Bearing Intermetallics for Impurity-Tolerant Recycled 6xxx Aluminum Sheet Alloys
Direct Atmospheric Sulfuric Acid Leaching of Low Nickel Matte: A New Hydrometallurgical Route for Selective Metal Recovery
Electrolyte Design for Sustainable Ironmaking: Electrowinning of High-Purity Iron from Low-Grade Oxide Ores
Evaluation of Recycled Ti-6Al-4V Powder Feedstock for use in Additive Manufacturing using In-situ X-Ray Diffraction
Fusing In-Situ Monitoring Data with Physics-Based Simulations for Real-Time Process-to-Structure Prediction in Metal AM Using Conditional Generative AI Model
Improving critical metals circularity in additive manufacturing by recovery and reuse of cold spray feedstock powders
Kinetic pathways of the oxide-to-metal conversation
Life Cycle Analysis-based Multi-Objective Optimization of H2-DRI charging in Scrap-Based EAF Steelmaking
Mechanism-Guided Upcycling of Downgraded Aluminum Scrap through Iron-Rich Intermetallic Trapping
Not so Idle Musings of Metallurgists: " Learnings From Lead Acid Battery Recycling that can be Applied to EV Battery Recycling
Predicting Melting Temperature of Molten Salt Electrolytes with Universal Machine Learning Interatomic Potentials
Predicting Mineral Phase Diagrams from First-Principles Modeling
Production of Low-Fe Aluminum Alloys through Efficient Iron Removal from Casting Scrap
Recent progress on recycling critical elements using plasma and solid-state methods
Recycling and Integration Challenges of Lithium–Sulfur Batteries in the Existing LIB Ecosystem
Secondary Aluminum Reductants in Ferrochromium Production
Solid state scrap processing: An overview of new approaches
Solidification Pathways in Al-Fe Alloys under Different Cooling Rates
Suppressing Fe-Rich Intermetallics in High-Fe Recycled Aluminum via Cooling-Rate Engineering and Nucleation Modeling
Sustainable Neodymium Metal Production via Magnesiothermic Reduction of Oxide
Synthesis of Li2S via the sulfidation of LiOH using H2S generated by the reaction of H2 with molten S
Textured Metals for Energy Storage: From Findings via Characterization to New Materials Design

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