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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Energy Technologies and CO2 Management: Resource Efficient Processes
Presentation Title Thermodynamic analysis of mineral phase regulation in steel slag for high-temperature modification coupled with carbonates
Author(s) Pengzhen LI, Ying Chen, Duo Li, Hongyan Yan
On-Site Speaker (Planned) Pengzhen LI
Abstract Scope To achieve the directional regulation of mineral phases and high-value utilization of steel slag, this study proposes a high-temperature modification strategy using carbonates as modifiers, and its feasibility was verified through thermodynamic analysis. The results show that, compared with the systems without modifiers or with Li2CO3 or K2CO3 as modifiers, Na2CO3 exhibits the most significant promoting effect on the mineral phase reconstruction of steel slag. Under Na2CO3 modification, the iron-bearing phases in steel slag, including the RO phase and Ca2Fe2O5, are transformed into magnetic iron oxides, which are enriched in the slag. Meanwhile, the original f-CaO in steel slag and the CaO released from mineral phase dissociation further react with CO2 to form CaCO3. This work provides a new technical route for the high-value resource utilization of steel slag.
Proceedings Inclusion? Planned:
Keywords Recycling and Secondary Recovery, Iron and Steel, Phase Transformations

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Thermodynamic analysis of mineral phase regulation in steel slag for high-temperature modification coupled with carbonates
Weather-Informed Electricity Price Forecasting for Flexible Metal Production
Zinc coordination-driven electrochemical CO2 capture in amino acid-based absorbents: absorption performance, desorption efficiency, and electrochemical behavior

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