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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Cutting-Edge Characterization and Electrochemical Techniques for Unraveling Corrosion Phenomena
Presentation Title Uncovering Atomic Scale Corrosion and Oxidation Mechanisms in Materials: Insights from Cryogenic Atom Probe Tomography and Atomic Force Microscopy
Author(s) Arun Devaraj, Tingkun Liu, Vukkum Venkata Bhuvaneswari, Jack Grimm, Semanti Mukhopadhyay, Matthew Olszta, Jinhui Tao
On-Site Speaker (Planned) Arun Devaraj
Abstract Scope Cryogenic transfer atom probe tomography (APT) and atomic force microscopy (AFM) offer powerful, complementary capabilities for nanoscale analysis of corrosion and oxidation processes. Cryo-transfer preserves environmentally sensitive features—such as hydrated corrosion products, passive films, and interfacial chemistries—by minimizing artifacts introduced during specimen preparation and exposure to ambient conditions. This is especially critical for studying alloys where surface reactions evolve rapidly upon environmental exposure. APT enables three-dimensional compositional mapping of corrosion fronts and interfaces with sub-nanometer resolution, while AFM provides high-resolution topographical imaging to reveal surface features such as pits, cracks, and passive film degradation. Together, these techniques facilitate correlative analysis of both chemistry and morphology, offering insights into corrosion initiation, localized attack, and the influence of nanoscale heterogeneities. This talk will highlight recent advancements in combining cryo-APT and AFM to investigate early-stage corrosion and oxidation mechanisms in structural and functional materials.
Proceedings Inclusion? Planned:
Keywords Characterization, Environmental Effects,

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A closer look at passive films upon multi principal element alloys
Advanced Mechanical Characterization of Chloride-Induced Stress Corrosion Cracking in Stainless Steel
Advanced Modeling Techniques for Efficient Discovery of Corrosion Phenomena
Application of Cutting-edge Materials Characterization Techniques to Understanding Stress Corrosion Cracking
Atomic-scale Understanding of Cu Effect on Mechanical, Antibacterial, and Corrosion Properties of Ultrahigh-strength Maraging Stainless Steel
Characterizing the mechanisms controlling localized corrosion of steel in concrete
Combined hydrogen permeation based potentiometry and electrochemical impedance spectroscopy technique to measure cathodic oxygen reduction kinetics at an organic coating/iron interface
Evaluating Passive Film Properties of Fe-Based Metallic Glasses for Enhanced Corrosion Resistance
Evaluation of SS316 Corrosion in a Flowing LiCl-KCl Environment with Real-Time Electrochemical Monitoring
Gathering Actionable Corrosion Data for Light Water Reactors and Molten Salt Reactors
Localized Hydrogen Irradiation of Metals Produced by Focused Ion Beam - Scanning Electron Microscope
Mapping the heterogeneous charge transport during oxidation of metals containing nanoscale metal inclusions with 4DSTEM and APT
Multimodal characterization of material degradation in nuclear environments
Non-Destructive Characterization of Metal-Coating Interface Revealing Corrosion Beneath the Coating
Perspectives on the development of oxidation-resistant alloys for Advanced Ultra-Supercritical power plants
Real-Time Atomic-Scale Imaging of Defect-Driven Oxidation Under Reactive Gases
Revisiting Transpassivity with a new lens: Transpassive corrosion mechanisms in Ni probed with in situ respirometry coupled electrochemical polarization
Scanning Kelvin Probe Techniques for Unraveling Corrosion Phenomena
Uncovering Atomic Scale Corrosion and Oxidation Mechanisms in Materials: Insights from Cryogenic Atom Probe Tomography and Atomic Force Microscopy
Understanding the Influence of Secondary Phase Particles on Localized Corrosion of Al A356 Alloy to Enable an Increased Use of Recycled Al
Whole-surface EBSD mapping for 1:1 correlation of grain structure and corrosion initiation

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