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Meeting MS&T26: Materials Science & Technology
Symposium Advances in Refractory High Entropy Alloys and Ceramics
Presentation Title Design and Validation of Tungsten-Based High Entropy Alloys
Author(s) Dan J. Thoma, Caleb Hatler, Matthew Vigil, Bochuan Sun, Enrique Martinez, Nathan Curtiss, Adrien Couet, Saryu Fensin, Skye Supakul, Ishtiaque Robin, Osman El Atwani
On-Site Speaker (Planned) Dan J. Thoma
Abstract Scope Development of refractory tungsten alloys for nuclear applications pose challenges to computationally design, experimentally test, and scale-up components for multi-objective performance objectives. This study investigates thermodynamic computational assessments in the absence of fully developed CALPHAD databases to computationally design and experimentally process, characterize and test alloys using high-throughput techniques. Compositions in the WTaVCrHf quinary system were calculated to promote BCC phase stability using both cluster expansion and CALPHAD methods. Over 75 alloy compositions were down selected and processed into 1 cm^3 samples via additive manufacturing. Automated indentation, X-ray diffraction, and irradiation were performed to select the best combination of properties. A final alloy was translated to laser powder bed fusion for testing and scale-up. Ambient temperature yield strengths of ~1.8 GPa were produced in an alloy that also had higher thermal conductivity than pure tungsten at 1273 K. This design and validation process has been extended to other refractory HEAs.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Multiscale Modeling Study of the Mechanical Response of W-Mo Alloys
A Nanoindentation Study of Incipient Plasticity in Refractory High-Entropy Alloys
Compositional Emptiness as a Guide to Alloy Discovery
Defect-Controlled Oxidation Resistance of (Ln, U)O2 solid solutions Probed by XAFS and XRD
Design and Validation of Tungsten-Based High Entropy Alloys
Design of Heterostructured Refractory Alloys for High Temperature Applications
Dislocation Properties in Refractory Compositionally Complex Alloys
Dominant Role of Second Nearest-Neighbor Bonding in Strength-Ductility Tradeoff of bcc Refractory High Entropy Alloys
Dynamic Behavior of NbTaTiHf High-Entropy Alloy
Multidimensional Diffraction Insights into Oxygen-Amplified Strengthening in BCC Refractory Alloys
Nb-Regulated Selective Oxidation in Al–V–Cr–Zr Refractory High-Entropy Alloys fabricated via Powder Metallurgy
Near Net Shape Formation of High Entropy Carbide by Reactive Flash Sintering
Phase stability and local bonding in high entropy UHTC transition metal carbides
PhaseForge: Accelerating Phase Stability Predictions for Frontier Materials Without CALPHAD Databases
Powering Tomorrow with AI-Driven High-Entropy Discovery
Refractory Compositionally Complex Ceramics, Nanocrystalline Alloys, and Dual-Phase Composites: From Material Discovery to Innovative Processing
Refractory High-Entropy Alloys For Compact Fusion
Superior Spall Strength and Toughness in Hf₂₆Nb₂₀Ti₃₁V₂₃ Relative to Previously Tested Refractory Multi-Component Alloys
Swift Heavy Irradiation in Sr-Based High-Entropy Perovskites
Tailored Approaches to High-Temperature Deformation in Refractory Systems
Temperature Dependence of Yield Strength in NbTaTiV-Based Refractory Complex Concentrated Alloys
Tension-Compression Asymmetry in HfNbTaTiZr Refractory High-Entropy Alloys Studied with In Situ Neutron Diffraction
Thermal conductivity of high entropy ceramics before and after irradiation
Thermodynamics of Mechanical Behavior in R-CCAs: Balancing Room-Temperature Tensile Ductility and High Temperature Strength

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