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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Next Generation Electrometallurgical Technologies for Metal Extraction, Refining, and Recycling
Presentation Title Closed-Loop Electrochemical Extraction and Recovery of Critical Minerals Using Low-Cost Open-Source Ion Exchange Membranes
Author(s) Robert Karas
On-Site Speaker (Planned) Robert Karas
Abstract Scope Membrane-divided electrolysis enables critical mineral recovery with in-situ reagent regeneration, but commercial membrane cost and fouling have blocked mining-scale adoption. We report a homogeneous ion exchange membrane made from pulverized commercial resin dispersed in a PVC or CPVC matrix, cast from solvent at materials cost below one dollar per square foot, roughly two orders of magnitude below commercial alternatives, with the recipe published under CERN-OHL-S v2. The membrane has operated for a year in acidic, high-ORP leach solutions. Built around it, the SEM TECH platform performs continuous closed-loop leaching and recovery: chloride oxidizers and hydrochloric acid are generated in situ from brine and electricity, and dissolved metals are recovered as mixed concentrates. Campaigns on raw ore, high-sulfide ore, tailings, and mine waste liquids produced concentrated mixed-metal powders with confirmed rhodium recovery. Preliminary estimates span 300 to 2200 kWh per ton. We present membrane fabrication, cell architecture, performance, and scale-up path.
Proceedings Inclusion? Planned:
Keywords Electrometallurgy, Hydrometallurgy, Recycling and Secondary Recovery

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Rotating Porous Cathode Electrolytic Cell for Quasi-Continuous, Sustainable Iron Powder Production from Copper Smelting Dust
Carbon Emissions Assessment of Steelmaking Routes for 40Cr Steel
Closed-Loop Electrochemical Extraction and Recovery of Critical Minerals Using Low-Cost Open-Source Ion Exchange Membranes
Decarbonizing metal extraction through molten salt electrolysis with non consumable anodes
Electrometallurgy for Lithium Extraction and Processing
Electrons as Reductants: Transforming Metal Production through Electrometallurgy
Engineering Transition Metal Oxide Electrode for Direct Lithium Extraction from Aqueous Brines
Evidence of Silicon Production from Fluxed End-of-Life Photovoltaic Glass via Molten Oxide Electrolysis
High-Temperature Molten Salt Electrolysis for Sustainable Small-Molecule Chemical Synthesis
Liquid-Metal Bipolar Membrane for Electrochemical Recovery of Critical Metals in Molten Salts
Molten Salt Electrolysis for Iron Production: Progress Toward Decarbonized Ironmaking
Nordic Salt Cycle – Scaling a Molten Salt Process for Critical Mineral Recovery to Pilot
Recovery of Valuable Metals From Secondary Resources Using Molten Oxide Electrolysis
Thermodynamic and Experimental Investigation of In-Furnace Recycling of Electric Arc Furnace Dust
Three-Layer Electrorefining of Liquid Zn and Pb Held on/in Porous Holding Materials in Molten Chlorides

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