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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Cutting-Edge Characterization and Electrochemical Techniques for Unraveling Corrosion Phenomena
Presentation Title Evaluation of SS316 Corrosion in a Flowing LiCl-KCl Environment with Real-Time Electrochemical Monitoring
Author(s) Ruchi Gakhar, Diego Macias, Qiufeng Yang
On-Site Speaker (Planned) Ruchi Gakhar
Abstract Scope This study presents corrosion testing of 316 stainless steel (SS316) in molten LiCl-KCl under controlled flow conditions using a custom flow loop testbed at Idaho National Laboratory (INL). A 500-hour high-temperature exposure was conducted with continuous molten salt circulation over SS316 coupons under well-characterized thermal and flow profiles. The system integrates in-line electrochemical sensors for real-time monitoring of salt chemistry, providing insight into corrosion kinetics and redox behavior. Periodic salt sampling and analysis via inductively coupled plasma (ICP) techniques quantified dissolved metal species and validated electrochemical data. The presentation will highlight the INL flow loop design, test conditions, corrosion behavior of SS316 in dynamic salt environments, and correlations between electrochemical signals and ICP analysis. These results support the development of effective corrosion monitoring approaches and inform material selection for advanced nuclear and thermal energy systems operating with molten chloride salts.
Proceedings Inclusion? Planned:
Keywords High-Temperature Materials, Environmental Effects, Characterization

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A closer look at passive films upon multi principal element alloys
Advanced Mechanical Characterization of Chloride-Induced Stress Corrosion Cracking in Stainless Steel
Advanced Modeling Techniques for Efficient Discovery of Corrosion Phenomena
Application of Cutting-edge Materials Characterization Techniques to Understanding Stress Corrosion Cracking
Atomic-scale Understanding of Cu Effect on Mechanical, Antibacterial, and Corrosion Properties of Ultrahigh-strength Maraging Stainless Steel
Characterizing the mechanisms controlling localized corrosion of steel in concrete
Combined hydrogen permeation based potentiometry and electrochemical impedance spectroscopy technique to measure cathodic oxygen reduction kinetics at an organic coating/iron interface
Evaluating Passive Film Properties of Fe-Based Metallic Glasses for Enhanced Corrosion Resistance
Evaluation of SS316 Corrosion in a Flowing LiCl-KCl Environment with Real-Time Electrochemical Monitoring
Gathering Actionable Corrosion Data for Light Water Reactors and Molten Salt Reactors
Localized Hydrogen Irradiation of Metals Produced by Focused Ion Beam - Scanning Electron Microscope
Mapping the heterogeneous charge transport during oxidation of metals containing nanoscale metal inclusions with 4DSTEM and APT
Multimodal characterization of material degradation in nuclear environments
Non-Destructive Characterization of Metal-Coating Interface Revealing Corrosion Beneath the Coating
Perspectives on the development of oxidation-resistant alloys for Advanced Ultra-Supercritical power plants
Real-Time Atomic-Scale Imaging of Defect-Driven Oxidation Under Reactive Gases
Revisiting Transpassivity with a new lens: Transpassive corrosion mechanisms in Ni probed with in situ respirometry coupled electrochemical polarization
Scanning Kelvin Probe Techniques for Unraveling Corrosion Phenomena
Uncovering Atomic Scale Corrosion and Oxidation Mechanisms in Materials: Insights from Cryogenic Atom Probe Tomography and Atomic Force Microscopy
Understanding the Influence of Secondary Phase Particles on Localized Corrosion of Al A356 Alloy to Enable an Increased Use of Recycled Al
Whole-surface EBSD mapping for 1:1 correlation of grain structure and corrosion initiation

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