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Meeting MS&T26: Materials Science & Technology
Symposium Advances in Refractory High Entropy Alloys and Ceramics
Presentation Title Compositional Emptiness as a Guide to Alloy Discovery
Author(s) Stéphane Gorsse, Daniel B. Miracle
On-Site Speaker (Planned) Daniel B. Miracle
Abstract Scope After over 20 years of intense study, there is not yet a compelling high entropy alloy (HEA) application. To explain this, recent work has demonstrated that most HEAs are compositionally similar to many commercial alloys, especially those based on 3d transition metals. This similarity is established by calculating and analyzing the compositional distances between nearly 1500 commercial alloys and HEAs. More detailed analysis shows that three principal elements are sufficient to achieve exceptional properties, and that one of those elements typically reach concentrations as high as 75 at.%. Here, we briefly review these findings as an introduction to a compositional emptiness analysis. This new approach identifies regions of multicomponent composition space that are farthest from commercial alloys and current HEAs. This analysis emphasizes compositional emptiness in the refractory element domain, to guide future work on RHEAs toward areas as yet untouched by both conventional alloys and the HEA approach.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Multiscale Modeling Study of the Mechanical Response of W-Mo Alloys
A Nanoindentation Study of Incipient Plasticity in Refractory High-Entropy Alloys
Compositional Emptiness as a Guide to Alloy Discovery
Defect-Controlled Oxidation Resistance of (Ln, U)O2 solid solutions Probed by XAFS and XRD
Design and Validation of Tungsten-Based High Entropy Alloys
Design of Heterostructured Refractory Alloys for High Temperature Applications
Dislocation Properties in Refractory Compositionally Complex Alloys
Dominant Role of Second Nearest-Neighbor Bonding in Strength-Ductility Tradeoff of bcc Refractory High Entropy Alloys
Dynamic Behavior of NbTaTiHf High-Entropy Alloy
Multidimensional Diffraction Insights into Oxygen-Amplified Strengthening in BCC Refractory Alloys
Nb-Regulated Selective Oxidation in Al–V–Cr–Zr Refractory High-Entropy Alloys fabricated via Powder Metallurgy
Near Net Shape Formation of High Entropy Carbide by Reactive Flash Sintering
Phase stability and local bonding in high entropy UHTC transition metal carbides
PhaseForge: Accelerating Phase Stability Predictions for Frontier Materials Without CALPHAD Databases
Powering Tomorrow with AI-Driven High-Entropy Discovery
Refractory Compositionally Complex Ceramics, Nanocrystalline Alloys, and Dual-Phase Composites: From Material Discovery to Innovative Processing
Refractory High-Entropy Alloys For Compact Fusion
Superior Spall Strength and Toughness in Hf₂₆Nb₂₀Ti₃₁V₂₃ Relative to Previously Tested Refractory Multi-Component Alloys
Swift Heavy Irradiation in Sr-Based High-Entropy Perovskites
Tailored Approaches to High-Temperature Deformation in Refractory Systems
Temperature Dependence of Yield Strength in NbTaTiV-Based Refractory Complex Concentrated Alloys
Tension-Compression Asymmetry in HfNbTaTiZr Refractory High-Entropy Alloys Studied with In Situ Neutron Diffraction
Thermal conductivity of high entropy ceramics before and after irradiation
Thermodynamics of Mechanical Behavior in R-CCAs: Balancing Room-Temperature Tensile Ductility and High Temperature Strength

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