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Meeting MS&T24: Materials Science & Technology
Symposium Preceramic Polymers; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title Development of Processable Polymer Derived Ultra-High Temperature Ceramics and Composites
Author(s) Timothy Pruyn, Jared Delcamp, Abigail Advincula, Sophia Angelopoulos, Matthew Dickerson
On-Site Speaker (Planned) Timothy Pruyn
Abstract Scope Ultra-high temperature ceramics (UHTCs) have garnered a great deal of interest as materials for extreme environments, but are challenging to process into complex components and ceramic matrix composites (CMCs). Preceramic polymers (PCPs) are one potential solution due to their unique ability to be converted from a workable polymeric material that can be processed into complex shapes and components, to a ceramic via heat treatment. Though PCPs are attractive for creating ceramics and composites, the vast majority of PCPs are silicon-based. This presentation will discuss a family of novel preceramic polymers that can form UHTCs carbides and nitrides. Along with creating a wide range of UHTC carbides and nitrides, these preceramics are inherently flowable, generate inorganic products in high yield (i.e., ≥50 wt%), can produce phase pure ceramics without excess carbon, and have tailorable compositions and rheology. This presentation will discuss the processing of these AFPCs into CMCs.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Ceramic Yields of Preceramic Polymer Grafted Nanoparticles using Conventional and Photothermal Heating
D-17: Structure and Properties of Preceramic Polymer Grafted Nanoparticle Monolayers
Developing Ceramic Materials via Preceramic Polymer Chemistry and an Enhanced Understanding of Structure-Property Relationships
Development of Processable Polymer Derived Ultra-High Temperature Ceramics and Composites
Formulation of Preceramic Polymers for Photocuring and 3D Printing of Polymer-Derived Ceramic Lattices
GNPs, NIMs, and UHTC AFPCs: Progress Toward Higher Volume Yielding Preceramics
Improving Mechanical Properties of Polymer-Derived Dense SiC Ceramics with the Integration of 2D MXene
Insights into MXene-SiOC Composite Formation and Properties via Experimental and DFT Studies
Phase and Microstructure Study of Boron-Doped Allylvinylhydridocarbosilane Derived Bulk SiBC Ceramic
Polymer Derived Ceramics: An Evolutionary Algorithm Driven Classical Molecular Dynamics
Preceramic Polymer Grafted Nanoparticle Systems
Refractory Ceramics Using High Char Polymers
Size Effects in Additively Manufactured Polymer-Derived Ceramic Composites
Thermo-Mechanical Effects during the Conversion of Pre-Ceramic Polymers

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