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Meeting MS&T25: Materials Science & Technology
Symposium Thermodynamics of Materials in Extreme Environments
Presentation Title Metal di-boride (MB2 | M = Ti, Zr, Nb, Hf, Ta) properties above 3000 ˚C
Author(s) Elizabeth Sobalvarro, Fox Thorpe, Jesus Rivera, Harry Charalambous, Gabrella King, James Cahill, Wyatt Du Frane, Joshua Kuntz, Scott J. Mccormack
On-Site Speaker (Planned) Scott J. Mccormack
Abstract Scope Metal diborides (MB2 | M = Ti, Zr, Nb, Hf, Ta) are considered an ultra-high temperature ceramic due to their relatively low reactivity and high melting point. This work will discuss high temperature levitation methods using a conical nozzle levitator system equipped with lasers to investigate the melting points and thermal expansion of the metal di-borides. The melting point will be investigated using a cooling trace experiments in conjunction with a 400 W CO2 laser and a 500 W Yb laser to melt metal di-boride samples. The thermal expansion will be investigated by coupling the levitation system with X-ray diffraction at Argonne National Laboratories Advanced Photon Source. The high temperature X-ray diffraction data was used to calculate anisotropic coefficients of thermal expansion. The coefficients were compared amongst the diborides. These thermophysical measurements will be critical in developing ultra-high temperature material systems for applications in nuclear fission/fusion reactors, and aerospace vehicles.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Achieving accurate entropy and melting point by ab initio molecular dynamics and zentropy theory: Application to fluoride and chloride salts
Computational tools for high temperature materials properties
First-Principles Thermodynamic Assessments of Sr-Containing Secondary Phase Formation in La1-xSrxMnO3±δ Perovskites for Solid Oxide Cell Applications
Inferring Structure from Raman Spectroscopy and Connecting It to the Macroscopic Behavior of Molten ThCl4
Larnite Ca2SiO4: high-temperature mass spectrometric study of thermodynamic properties
Metal di-boride (MB2 | M = Ti, Zr, Nb, Hf, Ta) properties above 3000 ˚C
Multiscale Prediction of α-Precipitate Nucleation in β-Stabilized Alloys: CALPHAD-based Model
Nanoparticle-Reinforced Polymers for Blast Mitigation Technologies
Thermochemical Stability of Oxides in High-Temperature, High-Velocity Steam
Thermodynamic Stability of Hydrated Rare Earth Carbonates (Lanthanites)
Ultra-lightweight single-phase Al-based complex concentrated alloy with high specific strength

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