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Meeting MS&T25: Materials Science & Technology
Symposium Thermodynamics of Materials in Extreme Environments
Presentation Title Thermochemical Stability of Oxides in High-Temperature, High-Velocity Steam
Author(s) Elizabeth J. Opila
On-Site Speaker (Planned) Elizabeth J. Opila
Abstract Scope High-temperature, high-velocity steam conditions are prevalent in power and propulsion applications and present challenging environments for materials durability. Test capabilities relevant for use in this environment are crucial for life prediction of materials undergoing thermochemical degradation mechanisms. In this presentation, a “steam-jet furnace” concept will be presented that is relevant for testing thermochemical stability of oxide-based environmental barrier coatings for SiC composite components used in the hot section of turbine engines. However, the capabilities of this test method go well beyond validating engineering applications, providing a tool for more fundamental materials science investigations. The presentation will address use of the steam-jet furnace to determine enthalpies of formation for gaseous metal hydroxides, complex oxide phase diagram determination, as well as the potential for oxide surface energy determination. Finally, remaining challenges in our understanding of the stability of complex oxides in high-temperature, high-velocity steam will be discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Achieving accurate entropy and melting point by ab initio molecular dynamics and zentropy theory: Application to fluoride and chloride salts
Computational tools for high temperature materials properties
First-Principles Thermodynamic Assessments of Sr-Containing Secondary Phase Formation in La1-xSrxMnO3±δ Perovskites for Solid Oxide Cell Applications
Inferring Structure from Raman Spectroscopy and Connecting It to the Macroscopic Behavior of Molten ThCl4
Larnite Ca2SiO4: high-temperature mass spectrometric study of thermodynamic properties
Metal di-boride (MB2 | M = Ti, Zr, Nb, Hf, Ta) properties above 3000 ˚C
Multiscale Prediction of α-Precipitate Nucleation in β-Stabilized Alloys: CALPHAD-based Model
Nanoparticle-Reinforced Polymers for Blast Mitigation Technologies
Thermochemical Stability of Oxides in High-Temperature, High-Velocity Steam
Thermodynamic Stability of Hydrated Rare Earth Carbonates (Lanthanites)
Ultra-lightweight single-phase Al-based complex concentrated alloy with high specific strength

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