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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Dilute Alloying and Impurity Effects on Phase Transformations
Presentation Title The Effect of Dilute Group VI Addition and Oxygen and Nitrogen Interstitials on Group IV-V Refractory High-Entropy Alloys
Author(s) Jacob Pustelnik, Mingwei Zhang, Edmund Dich
On-Site Speaker (Planned) Jacob Pustelnik
Abstract Scope Nb based refractory high entropy alloys (RHEAs) have garnered interest due to their room temperature ductility and strength retention at elevated temperatures. Unfortunately, these materials lack the high strength compared to current Ni-based superalloys. Recent research has looked specifically at NbTaTiV and attempted to include group VI elements (Cr, Mo, and W) to increase the high temperature strength. However, the inclusion of these elements has shown to cause a phase instability particularly with Ti segregating to the grain boundaries (GBs) which form a network of brittle material. To prevent the segregation of Ti in these materials, the origins of why the Ti segregates to the GBs were investigated in the NbTaTiV system with dilute W addition regards to two primary hypotheses: 1. The Ti segregation is caused by W repelling oxygen/nitrogen interstitials at the GBs. 2. The Ti segregation is caused directly by the miscibility gap with W addition.
Proceedings Inclusion? Planned:
Keywords Mechanical Properties, High-Entropy Alloys, High-Temperature Materials

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Achieving Linear Superelasticity in NiTi via Compositionally Modulated Martensitic Transformations: A Phase-Field Study
Alumina Formation Criteria for Low-Al Ductile Single-phase Refractory Multiprincipal Element Alloys
Atomic-Scale Insights into Dilute Alloying and Impurity Effects on Phase Transformations
Crystallographic Phase Behavior of Near Equiatomic FeNi Alloys with Dilute Phosphorus Addition
Cu-Enabled NiAl Precipitation in a Mn-Stabilized Austenitic Steel
Design of radiation-resistant copper alloys using synergistic solutes
Dilute Compositional Modulation as a Design Lever for Martensitic Transformation in NiTi Shape Memory Alloys
Effects of Sb alloying on the morphology of In2Te3-precipitates dispersed in the thermoelectric Bi2Te3-based matrix
Fast-Diffusing Solute Clusters and Pre-Existing Short-Range Order in the Nucleation of L1₂ Precipitates in a Ni–Al–Cr Alloy
Impurity effects on heterogeneous nucleation and morphological development of copper-rich secondary phases in entropy-stabilized oxides
Influence of Sn Microalloying on the Nucleation and Growth of L12-Al3Zr Precipitates in Dilute Al-Zr Alloys
Investigating Mechanical Performance of the Al4Ca Intermetallic Phase with Sr and Ba Microalloying Additions
Investigating the Liquidus Temperature of CaTi2Al20 in the Al-Ca-Ti System Using LP-LIBS and CALPHAD Modeling
Multiscale x-ray imaging reveals the impact of Cu on Fe–Mn intermetallics in recycled aluminum
The Effect of Dilute Group VI Addition and Oxygen and Nitrogen Interstitials on Group IV-V Refractory High-Entropy Alloys
The Effect of Magnesium Content on the Inclusions and Microstructure in Rare-Earth-Treated X80 Pipeline Steel
The effect of solute selection on second-phase particle structure and coherency in nanocrystalline copper

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