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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Biosustainable Materials for a Circular Economy
Presentation Title Free Radical Polymerization of Tulipalin A For Resin Applications
Author(s) Jennifer Vail, Jeff Bates
On-Site Speaker (Planned) Jennifer Vail
Abstract Scope Tulipalin A (α-methylene-γ-butyrolactone), a bio-based monomer derived from tulip bulbs, offers a sustainable alternative to petrochemical resins. Free radical polymerization of tulipalin A was studied under both thermal and UV curing conditions. In thermal curing, initiators such as ammonium persulfate and a co-initiator like N,N,N′,N′-tetramethylethylenediamine enabled crosslinking. For UV curing, the polymerization was initiated with a photoinitiator such as 2,2-dimethoxy-2-phenylacetophenone. The findings demonstrate that tulipalin A can be adapted for different resin applications by adjusting the curing method and adding fillers, offering a renewable alternative to petroleum-based polymers.
Proceedings Inclusion? Planned:
Keywords Biomaterials, Sustainability, Polymers

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