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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Advances in Ceramic Materials and Processing
Presentation Title High-temperature investigation of the thermodynamic properties of Ca3SiO5 hartrurite
Author(s) Sergey I. Shornikov
On-Site Speaker (Planned) Sergey I. Shornikov
Abstract Scope Hartrurite (alite) is one of the most important components of the Portland clinker. The Ca3SiO5 evaporation was studied by the Knudsen effusion mass spectrometry at 1750-2300 K. The partial pressures of the vapor species (Ca, CaO, SiO, SiO2, Si2O2, CaSiO3, O, O2) over Ca3SiO5 have been determined for the first time. The obtained oxide activities made it possible to determine the mixing energy in hartrurite, as well as the enthalpy and entropy of its formation. The presented high-temperature thermodynamic data are consistent with the available experimental information.
Proceedings Inclusion? Planned:
Keywords Ceramics, High-Temperature Materials, Characterization

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