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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Environmental Degradation of Multiple Principal Component Materials
Presentation Title Observing hydrogen trapping in a L12-precipitate-strengthened CoCrNi(TiAl) alloy
Author(s) Eason Yi-Sheng Chen
On-Site Speaker (Planned) Eason Yi-Sheng Chen
Abstract Scope Hydrogen embrittlement (HE) poses a significant challenge to the safe operation of metallic components in hydrogen-rich environments. Coherent nanoprecipitation offers a promising strategy to mitigate HE while enhancing strength and ductility. This study examines hydrogen trapping in L12-Ni3(Al, Ti) coherent nanoprecipitates within CoCrNi multi-principal-element alloys using deuterium pre-charged cryogenic atom probe tomography, aberration-corrected transmission electron microscopy, and density functional theory calculations. Our results reveal that hydrogen predominantly accumulates within the octahedral interstitial sites of L12 (γʹ-type) precipitates, driven by their highly negative hydrogen solution energy. This trapping mechanism, distinct from precipitate interface or matrix accumulation, offers simultaneous alloy strengthening and low HE susceptibility, overcoming the traditional strength-HE resistance trade-off. These insights guide the design of high-strength, HE-resistant alloys for hydrogen-rich environments.
Proceedings Inclusion? Planned:
Keywords High-Entropy Alloys, Characterization, Sustainability

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Accelerated Discovery of Corrosion-Resistant Co-Cr-Fe-Ni High-Entropy Alloys via Deep Learning
Accelerated Discovery of Oxidation-Resistant Refractory Compositionally Complex Alloys via High-Throughput Diffusion Multiples and Active Learning.
Computational Design of Cost-Effective Multi-Functional Environmental Barrier Coatings
Data-Driven Prediction of Materials Electrochemical Stability
Design and evaluation of low-cost multicomponent rare earth disilicate environmental barrier coatings
Dislocations and multiphase states in high entropy oxides
Effect of Heat Treatment on the microstructure of two FeCrNi-Based MPEAs and their response to ion irradiation
Experimental measurement and theoretical assessment of oxidation behavior of dual-phase CoCrNiCu0.5 alloy.
Extensive Corrosion of Economizer Finned Tubes Made of SA 178 Grade A
High-throughput mapping of properties of CoNiX for improved erosion resistance
Hydrogen Diffusion and Twin-Assisted Embrittlement in CoCrFeMnNi High-Entropy Alloy at Cryogenic Conditions
Magnetic nanoparticles of (Al0.6Mn0.6Fe0.6Co0.6Ni0.6)O4 High entropy oxide for photocatalytic degradation of organic dye
Magnetic nanoparticles of (Al0.6Mn0.6Fe0.6Co0.6Ni0.6)O4 Hign entropy Oxide for photocatalytic degradation of organic dye
Observing hydrogen trapping in a L12-precipitate-strengthened CoCrNi(TiAl) alloy
Oxidation-Modeling for Alloy Performance Using Machine Learning Algorithms
Performance of AM NiCoCr-based Alloys: Cyclic Oxidation in Air and Air-Steam Environments
Probing irradiation-induced void swelling in CrFeMnNi compositionally complex alloys using high-throughput irradiation and characterization methods
Study on a Synergetic Effect of Multiple Elements on the Passivation Behavior of Alx(FeNiVTi)100-x alloys
Tantalate as a Novel Grown Oxide to Protect Refractory Metal Alloys
The third element effect on Aqueous Passivity in Cr containing 3-d Transition based Ternary, Quaternary, and Compositionally Complex Alloys
Tuning the oxidation behavior of Nb-Mo-Ti-Al-X alloys at intermediate temperatures
Understanding the Interaction of Hydrogen With Various Defects in MP35N Alloy
Unveiling hidden mechanisms on High Entropy Alloys to counteract hydrogen embrittlement
Variable-Temperature Plasmonic High-Entropy Carbides

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