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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium External Field-Intensified Materials Processing
Presentation Title Synthesis of High-Purity Cadmium Telluride by Pressurized Smelting - Vacuum Purification
Author(s) Jiarong Li, Guozheng Zha, Wenlong Jiang
On-Site Speaker (Planned) Wenlong Jiang
Abstract Scope This work presents an energy-efficient method for synthesizing 5N-purity (≥99.999%) cadmium telluride (CdTe) at significantly reduced temperatures. Tellurium and cadmium (both ≥99.999% purity) are mixed in a molar ratio of 1:1.1 and subjected to pressurized smelting under 0.4–0.6 MPa in an inert atmosphere (N₂/Ar) at 450–500°C for 60–150 min. The elevated pressure enables a >300°C reduction in synthesis temperature compared to conventional methods (≥800°C). The resulting CdTe crude product is then purified under vacuum (1–20 Pa) at 450–500°C for 30–90 min. Crucially, the process achieves a yield exceeding 98.5% post-purification (validated at 500°C/0.5 MPa) while maintaining 99.999% purity. This represents a paradigm shift in CdTe manufacturing, dramatically lowering energy consumption without compromising yield or purity for semiconductor applications (e.g., solar cells, radiation detectors).
Proceedings Inclusion? Planned:

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A Review: Microwave Processing for Sustainable Ironmaking
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Interaction Mechanisms and Kinetic Characteristics of Microwave Calcination for Preparing Molybdenum Trioxide from Complex Molybdenum Concentrates
Magnetic Field-Assisted Additive Manufacturing of Rare-Earth-Free AlNiCo Magnets
Process and Kinetics of Preparing Antimony Trioxide by Microwave Oxidation of Volatile Antimony-Sulfur-Oxygen Mixed Ore
Surface Crack Healing in Ni-Based GH4169 Alloy Under Pulsed Current
Synthesis of High-Purity Cadmium Telluride by Pressurized Smelting - Vacuum Purification

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