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Meeting MS&T26: Materials Science & Technology
Symposium Molecular Approaches to Ceramics; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title Advances in the Processing of Ceramic Matrix Composites (CMCs) by Polymer Infiltration and Pyrolysis (PIP)
Author(s) Matthew B. Dickerson
On-Site Speaker (Planned) Matthew B. Dickerson
Abstract Scope High- and ultra-high-temperature ceramic matrix composites (CMCs) are essential materials in aerospace applications, primarily due to their high service temperature, oxidation resistance, and low ablation rate. The materials community is actively developing and utilizing numerous processing methods to synthesize dense, non-oxide composites. While techniques such as reactive melt infiltration (RMI), chemical vapor infiltration (CVI), and hot-pressing each offer advantages, the Air Force Research Laboratory (AFRL) Ceramics Research Team has focused its efforts on advancing polymer infiltration and pyrolysis (PIP)-based processing of CMCs. This presentation will provide an overview of AFRL's advancements in PIP-based CMCs, with a specific emphasis on processing CMCs using commercially available polycarbosilanes. A key focus will be a detailed discussion of the chemistry, processing, structure, and property relationships inherent in PIP-based CMCs.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A ReaxFF Force Field for Atomistic Simulation of Tantalum Carbide Formation via Reactive Sputtering and Polymer Pyrolysis
A Systematic Approach to Enhancing the Oxidation Resistance of C/C Composites Using Multi-Layer SiC–ZrB₂-Based Coatings
Additive Manufacturing of Variable-Composition and Difficult-to-Print Ceramics Based on Preceramic Polymers
Advances in Materials for Extreme Environment Applications
Advances in the Processing of Ceramic Matrix Composites (CMCs) by Polymer Infiltration and Pyrolysis (PIP)
Building a PDC Genome: AI-Assisted Extraction and Gap Analysis of Preceramic Polymer Descriptors
Characterization of Processing-Induced Stress and Crack Formation in Polymer-Derived Ceramics During Pyrolysis
Chemical and Structural Evolution of MXene-SiOC Under Ground- and Micro-Gravity and Controlled Atmospheres
Deep Learning-Based Framework for ReaxFF Development in Reactive Material Systems
Design and Manufacturing of New Functional Ceramic Composites
Development and Application of ReaxFF Reactive Force Fields to Ceramics Synthesis and High-Temperature Ceramics Response
Development of a ReaxFF Reactive Force Field for the Investigation of Thermochemical, Thermophysical and Oxidation Behavior of Titanium Diboride
Development of MS-154 as a Lower-Cost Preceramic Polymer Route for SiC-Containing Ceramics
Development of the ReaxFF Reactive Force Field for Zirconium Carbide Ceramic Formation During Sputtering
Engineering with Carbosilane
From Single-Source Precursors to Compositionally Complex (Hf-Ti-Nb-W-V)CN Carbonitrides
Improved Electrochemical Stability of Lithium–Sulfur Batteries Using SiBCN Sulfur Hosts
Kinetics of Pyrolysis Measured During In-Situ Creep Experiments
Lignin-Silicon Hybrid Ceramic Structures: Chemically Active versus Passive Colloids in Preceramic Sol-Gel Systems
Molecularly Engineered Refractory-Metal Preceramic Inks for Printable Ultrahigh-Temperature Ceramic Coatings
Nanoscale Structural Evolution in Polycarbosilane-Derived Ceramics
Phase Evolution Study of Polymer Derived SiC and TiC-SiC Composites Under Ultrafast Heating
Photo-Rheology of Ceramic-Filled Preceramic Polymers for Material Extrusion Additive Manufacturing
Polymer-Derived SiTiOC Ceramics for Enhanced Polysulfide Confinement in Lithium–Sulfur Cells
Processing and Pyrolysis Effects in Polymer Derived Ultra-High Temperature Ceramics
Tailoring Polymer Grafted Nanoparticle Properties Via Modification of Polymer Structure and Nanoparticle Composition
The Influence of Residual Copper Catalyst on the Polymer-to-Ceramic Conversion of a Click-Derived Polycarbosilane
Understanding Pyrolysis of Polymer-Derived Carbonitrides Through Ab Initio-Based Machine Learning Interatomic Potential
Use of Embedded Oxidation Marker Particles to Track Oxidant Ingress in Heterogeneous Microstructures Produced from Polymer Derived Ceramics
Visualizing Polymer to Ceramic Transformations in SiOC Polymer Derived Ceramics with In Situ Transmission Electron Microscopy

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