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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Environmental Degradation of Multiple Principal Component Materials
Presentation Title Tuning the oxidation behavior of Nb-Mo-Ti-Al-X alloys at intermediate temperatures
Author(s) Melina A. Endsley, Collin S. Holgate, Kirmina M. Monir, Eddy L. Rao, Michael Worku, Carlos G. Levi, Tresa M. Pollock
On-Site Speaker (Planned) Melina A. Endsley
Abstract Scope Refractory multi-principal element alloys (RMPEAs) are promising candidates for replacing Ni-based superalloys in gas turbine engines due to their exceptional strength at high temperatures. However, these alloys generally exhibit poor oxidation resistance, and will therefore require overlay protective coatings, which historically have gained protection from the formation of an alumina scale. Unfortunately, current alumina-forming bond coats have inadequate temperature capabilities and are thermochemically incompatible with state-of-the-art RMPEAs, motivating the design of new environmental coatings. Previous work has explored the Nb-Mo-Ti-Al composition space, where new alloys formed a continuous and adherent alumina scale at 1400°C, but performed poorly at 1200°C, experiencing runaway oxidation. To mitigate this intermediate temperature oxidation, alloy variants with additions of 5 at% Hf, Cr, or Si were synthesized and tested. The resultant oxidation behavior and microstructural differences are analyzed via various characterization techniques, including EPMA and TEM. Oxidation kinetics, assessed by TGA, will also be discussed.
Proceedings Inclusion? Planned:
Keywords Environmental Effects, High-Temperature Materials, Other

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Accelerated Discovery of Corrosion-Resistant Co-Cr-Fe-Ni High-Entropy Alloys via Deep Learning
Accelerated Discovery of Oxidation-Resistant Refractory Compositionally Complex Alloys via High-Throughput Diffusion Multiples and Active Learning.
Computational Design of Cost-Effective Multi-Functional Environmental Barrier Coatings
Data-Driven Prediction of Materials Electrochemical Stability
Design and evaluation of low-cost multicomponent rare earth disilicate environmental barrier coatings
Dislocations and multiphase states in high entropy oxides
Effect of Heat Treatment on the microstructure of two FeCrNi-Based MPEAs and their response to ion irradiation
Experimental measurement and theoretical assessment of oxidation behavior of dual-phase CoCrNiCu0.5 alloy.
Extensive Corrosion of Economizer Finned Tubes Made of SA 178 Grade A
High-throughput mapping of properties of CoNiX for improved erosion resistance
Hydrogen Diffusion and Twin-Assisted Embrittlement in CoCrFeMnNi High-Entropy Alloy at Cryogenic Conditions
Magnetic nanoparticles of (Al0.6Mn0.6Fe0.6Co0.6Ni0.6)O4 High entropy oxide for photocatalytic degradation of organic dye
Magnetic nanoparticles of (Al0.6Mn0.6Fe0.6Co0.6Ni0.6)O4 Hign entropy Oxide for photocatalytic degradation of organic dye
Observing hydrogen trapping in a L12-precipitate-strengthened CoCrNi(TiAl) alloy
Oxidation-Modeling for Alloy Performance Using Machine Learning Algorithms
Performance of AM NiCoCr-based Alloys: Cyclic Oxidation in Air and Air-Steam Environments
Probing irradiation-induced void swelling in CrFeMnNi compositionally complex alloys using high-throughput irradiation and characterization methods
Study on a Synergetic Effect of Multiple Elements on the Passivation Behavior of Alx(FeNiVTi)100-x alloys
Tantalate as a Novel Grown Oxide to Protect Refractory Metal Alloys
The third element effect on Aqueous Passivity in Cr containing 3-d Transition based Ternary, Quaternary, and Compositionally Complex Alloys
Tuning the oxidation behavior of Nb-Mo-Ti-Al-X alloys at intermediate temperatures
Understanding the Interaction of Hydrogen With Various Defects in MP35N Alloy
Unveiling hidden mechanisms on High Entropy Alloys to counteract hydrogen embrittlement
Variable-Temperature Plasmonic High-Entropy Carbides

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