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Meeting 2027 TMS Annual Meeting & Exhibition
Symposium Circular Metallurgy: Design, Technology, Application
Presentation Title Suppressing Fe-Rich Intermetallics in High-Fe Recycled Aluminum via Cooling-Rate Engineering and Nucleation Modeling
Author(s) Kyaw Hla Saing Chak, Sammel M William, Koustav Dey, Sunyong Kwon, Jie Huang, Ying Yang, Yijia Gu
On-Site Speaker (Planned) Yijia Gu
Abstract Scope Recycling aluminum reduces energy use by up to 95% relative to primary production, but structural use of recycled Al is limited by elevated Fe, which promotes coarse, brittle Fe-rich intermetallic compounds (FeRICs) during solidification. This work presents a predictive strategy to suppress FeRIC formation in high-Fe recycled aluminum through cooling-rate engineering and nucleation modeling. Using wedge-mold casting with a high-fidelity fiber-optic temperature sensor, we quantify cooling-rate-dependent phase selection in Al alloys containing 2–3 wt% Fe. We show that FeRIC formation can be fully suppressed at high cooling rates (~500 K s⁻¹), in agreement with a phase-selection model predicting the critical cooling rate needed to bypass FeRIC nucleation. These results define processing windows for controlling deleterious intermetallics without costly alloy additions and are directly relevant to rapid-solidification processes such as die casting, welding, and additive manufacturing, enabling higher recycled content in structural aluminum.
Proceedings Inclusion? Undecided
Keywords Recycling and Secondary Recovery, Aluminum, Solidification

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Thermodynamics-Guided Computational Framework for the Sustainable Design of Secondary Aluminium Alloys for Packaging Applications
Additive Manufacturing of Metals: From Complex Alloys to Simple Alloys
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Alkali-Based Hydrogen Reduction of Molybdenite: A Review of Process and Research Progress
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Controlling Iron-Bearing Intermetallics for Impurity-Tolerant Recycled 6xxx Aluminum Sheet Alloys
Direct Atmospheric Sulfuric Acid Leaching of Low Nickel Matte: A New Hydrometallurgical Route for Selective Metal Recovery
Electrolyte Design for Sustainable Ironmaking: Electrowinning of High-Purity Iron from Low-Grade Oxide Ores
Evaluation of Recycled Ti-6Al-4V Powder Feedstock for use in Additive Manufacturing using In-situ X-Ray Diffraction
Fusing In-Situ Monitoring Data with Physics-Based Simulations for Real-Time Process-to-Structure Prediction in Metal AM Using Conditional Generative AI Model
Improving critical metals circularity in additive manufacturing by recovery and reuse of cold spray feedstock powders
Kinetic pathways of the oxide-to-metal conversation
Life Cycle Analysis-based Multi-Objective Optimization of H2-DRI charging in Scrap-Based EAF Steelmaking
Mechanism-Guided Upcycling of Downgraded Aluminum Scrap through Iron-Rich Intermetallic Trapping
Not so Idle Musings of Metallurgists: " Learnings From Lead Acid Battery Recycling that can be Applied to EV Battery Recycling
Predicting Melting Temperature of Molten Salt Electrolytes with Universal Machine Learning Interatomic Potentials
Predicting Mineral Phase Diagrams from First-Principles Modeling
Production of Low-Fe Aluminum Alloys through Efficient Iron Removal from Casting Scrap
Recent progress on recycling critical elements using plasma and solid-state methods
Recycling and Integration Challenges of Lithium–Sulfur Batteries in the Existing LIB Ecosystem
Secondary Aluminum Reductants in Ferrochromium Production
Solid state scrap processing: An overview of new approaches
Solidification Pathways in Al-Fe Alloys under Different Cooling Rates
Suppressing Fe-Rich Intermetallics in High-Fe Recycled Aluminum via Cooling-Rate Engineering and Nucleation Modeling
Sustainable Neodymium Metal Production via Magnesiothermic Reduction of Oxide
Synthesis of Li2S via the sulfidation of LiOH using H2S generated by the reaction of H2 with molten S
Textured Metals for Energy Storage: From Findings via Characterization to New Materials Design

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