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Meeting MS&T24: Materials Science & Technology
Symposium Preceramic Polymers; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title GNPs, NIMs, and UHTC AFPCs: Progress Toward Higher Volume Yielding Preceramics
Author(s) Jared Delcamp, Matthew Dickerson, Timothy Pruyn, Kara Martin, Christina Thompson, Nicholas Posey, Brandon Ackley, Abigail Advincula, Sophia Angelopoulos
On-Site Speaker (Planned) Jared Delcamp
Abstract Scope Ceramic matrix composites (CMCs) as refractory materials can provide enhanced capabilities for many structural systems exposed to elevated temperatures. Fabrication of CMCs can be dramatically improved with respect to ceramic filling of tight spaces within fiber weaves from the infiltration of a liquid preceramic materials followed by pyrolysis to yield the desired ceramic. However, improvements to the ceramic yield, material purity, and availability of the types of ceramics formed during this process are desirable. This presentation will focus primarily on two approaches for improving ceramic volume yield from preceramics: polymer grafted nanoparticles (GNPs) and liquid ultra-high temperature ceramics (UHTCs). The design and properties of the preceramics as well as the use of these materials in carbon fiber weave-based composites will be discussed. A range of resulting ceramic will be discussed with a focus on preceramics generating SiC and ZrC. HfC, TiC, and some high-entropy/compositionally complex ceramics will be briefly discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Ceramic Yields of Preceramic Polymer Grafted Nanoparticles using Conventional and Photothermal Heating
D-17: Structure and Properties of Preceramic Polymer Grafted Nanoparticle Monolayers
Developing Ceramic Materials via Preceramic Polymer Chemistry and an Enhanced Understanding of Structure-Property Relationships
Development of Processable Polymer Derived Ultra-High Temperature Ceramics and Composites
Formulation of Preceramic Polymers for Photocuring and 3D Printing of Polymer-Derived Ceramic Lattices
GNPs, NIMs, and UHTC AFPCs: Progress Toward Higher Volume Yielding Preceramics
Improving Mechanical Properties of Polymer-Derived Dense SiC Ceramics with the Integration of 2D MXene
Insights into MXene-SiOC Composite Formation and Properties via Experimental and DFT Studies
Phase and Microstructure Study of Boron-Doped Allylvinylhydridocarbosilane Derived Bulk SiBC Ceramic
Polymer Derived Ceramics: An Evolutionary Algorithm Driven Classical Molecular Dynamics
Preceramic Polymer Grafted Nanoparticle Systems
Refractory Ceramics Using High Char Polymers
Size Effects in Additively Manufactured Polymer-Derived Ceramic Composites
Thermo-Mechanical Effects during the Conversion of Pre-Ceramic Polymers

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