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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Advances in the State-of-the-Art of High Temperature Alloys
Presentation Title Effect of Alloying Elements on Surface Oxidation Behavior of Gas-Atomized Ni-Based Powders
Author(s) Dae-Hyeon Kim, May Likha Lwin, Geon-woo Baek, Hyunjoong Kim, Jaehyeok Sim, Jiwoon Lee, Ho Jin Ryu, Soon-Jik Hong
On-Site Speaker (Planned) Dae-Hyeon Kim
Abstract Scope This study examines the influence of alloying elements on the surface oxidation behavior of gas-atomized Ni-Cr-Al and Ni-Cr-Al-Fe (Haynes 214 grade) powders, with relevance to powder metallurgy and additive manufacturing. Surface analyses via X-ray Photoelectron Spectroscopy (XPS) and Auger Electron Spectroscopy (AES) revealed that Fe addition significantly modifies the oxidation mechanism by suppressing Al₂O₃ formation and stabilizing a thin, uniform Ni–Cr-rich oxide layer. In contrast, the Fe-free Ni-Cr-Al powders showed rougher surfaces with localized Al₂O₃ particulates (~2 nm), indicating uneven oxidation. High-temperature oxidation (~1150 °C) resulted in protective Cr₂O₃ and spinel layers in both powders, but Al diffusion and oxide thickening were more pronounced in Ni-Cr-Al. The results underscore the synergistic role of Cr and Al in forming protective oxides, while highlighting Fe’s role in enhancing surface stability. These findings offer insight into alloy design for improving oxidation resistance and thermal performance in Ni-based powder systems.
Proceedings Inclusion? Planned:
Keywords Copper / Nickel / Cobalt, High-Temperature Materials, Powder Materials

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

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C-6: Optimization in Mechanical Properties of Inconel 939-Type Nickel-Based Superalloys
C-7: Physics Based Simulations of Competitive Grain Growth in Nickel Superalloys
C-8: The Effect of CoAl2O4 as a Nucleating Agent and Pouring Temperature on the Microstructure and Properties of Inconel 713CŪ Nickel-Based Superalloy Castings
Designing Next Generation Superalloys by Revealing Atomic-Scale Solute-Defect Interactions in Creep Deformed CMSX4 Superalloy
Development of Oxidation-Resistant Cr-Mo-Si Solid Solution Alloys
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Effect of Heat Treatment Cooling Rates on Microstructure and High Temperature Creep Properties of Nickel Based Superalloys
Effect of Precipitate Types and Distribution on Grain Refinement During Hot Deformation of Inconel
Effects of Titanium Nitride Layer on High-Temperature Oxidation of Titanium Alloys
Elemental Segregation and Diffusion Driven Recrystallization and Grain Refinement During Carburization of Ni-Cr-Fe- Based Alloy
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Microstructure and Strength of Additively Manufactured, Oxide Dispersion- and Precipitation-Strengthened Superalloys
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Unraveling Hydrogen Effects in Superalloys
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