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Meeting MS&T26: Materials Science & Technology
Symposium Phase Transformations in Ceramics: Science and Applications
Presentation Title Thermodynamic Design and Environmentally Controlled Synthesis of Soft Magnetic Ferrite-Metal Nanocomposites
Author(s) Paul R. Ohodnicki, Azhagu Dhanapal, Bishal Bhandari, Zisong Wang, Suraj Mullurkara
On-Site Speaker (Planned) Paul R. Ohodnicki
Abstract Scope Soft magnetic ferrite—metal composites overcome limitations of low saturation flux densities of ferrites used in high frequency power electronic applications to aid component miniaturization. Environmentally controlled synthesis involves synthesizing ferrite powders using conventional solid-state reaction including thermal processing with controlled gas atmospheres during sintering and/or through a subsequent additional processing step to selectively form metal nanoprecipitates in a ferrite matrix. Composite thermodynamic stability is modeled using Thermo-Calc to provide guidance for composition and processing windows that selectively convert cations to ferromagnetic metal precipitates embedded within the ferrite matrix while suppressing secondary oxide formation. Structural and magnetic characterization of phase fraction, nano/microstructure, precipitate composition, static, and dynamic magnetic properties are presented. Increases in saturation magnetization >~ 25% are demonstrated to date compared to base spinel ferrites. Current progress and future optimization pathways targeting scalable processing of high-performance nanocomposites with tailored magnetic properties are discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Assessing JMAK Kinetics Underlying Mechanochemical Phase Transformations
Behavior of Shape Memory Ceramic-Metal Matrix Composites under Mechanical and Thermal Stimuli
Ceramics for Water, Health, and Sanitation in Low- and Middle-Income Countries: Current and Future Applications
Characterizing Rare Earth Sesquioxide Phase Transformations Induced by High-Energy Ball Milling
Coarse-Graining Rare Events in Ceramic Microstructures Using Extended Volumes, Time Cones, and Hazard Kinetics
Correspondences in the Martensitic Transformation of Zirconia
From Clay to Capability: Multisensory Exploration of Material Properties and Structural Behavior in Ceramic Learning
Gasochromic Phase Transitions in Hybrid Nickel Halides
Grain Boundary Phase-Like Transitions: From Computing Grain Boundary Phase Diagrams to Engineering Microstructural Evolution Using Electric Fields
Influence of Compositional Complexity on Transformations in Pyrochlore Oxides Under Highly Ionizing Radiation
Non-Equilibrium Phase Transformations in Swift Heavy Ion Irradiated Rare-Earth Sesquioxides
The Potential of Solid-State NMR Investigations for Characterizing Phase Transformations in Calcium Aluminate Cements During the Hydration Process
Thermodynamic Design and Environmentally Controlled Synthesis of Soft Magnetic Ferrite-Metal Nanocomposites
Thermodynamic Mapping of High-Entropy-Like Brannerite Wasteform Ceramics Using integrated Calorimetry and Data-Driven Methods

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