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Meeting MS&T25: Materials Science & Technology
Symposium Engineering Ceramics: Microstructure-Property-Performance Relations and Applications
Presentation Title Finite Element Modeling of Microwave-Assisted Calcination of SOEC Perovskite Precursor Powders
Author(s) Hongwei Liu, Ansan Pokharel, Logan Proud, Brandon Robinson, Jianli Hu, Katarzyna Sabolsky, Javier Mena, Tugrul Yumak, Ashley Daniszewski, Christina Wildfire, Edward Sabolsky, Terence Musho
On-Site Speaker (Planned) Hongwei Liu
Abstract Scope Solid-oxide electrolysis cells (SOECs) offer great potential for efficient hydrogen production but face challenges related to scalable manufacturing. Microwave-assisted calcination of precursor powders provides a promising route to address scalability limitations. Precise thermal control during calcination is essential for preserving phase purity in subsequent sintering steps. To enhance process control, a fully coupled electromagnetic-thermal finite element model was developed using COMSOL Multiphysics. The model accurately represents the experimental microwave furnace geometry, including a heterogeneous packed bed of solid precursor particles. Simulations employ a two-way coupling scheme, integrating temperature-dependent dielectric properties with transient heat transfer and radiative interactions at particle surfaces. Results highlight how particle size and dielectric constants significantly influence microwave energy absorption, causing preferential heating in larger particles with higher dielectric values. Due to low particle thermal conductivity, interparticle heat transfer occurs predominantly via radiative exchange, informing strategies for optimized cavity design and susceptor placement to improve calcination uniformity.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

A Statistical Model of Microstructural Toughening in Ceramics
Breaking the Charge Neutrality Boundary in Perovskite Using the PyCALPHAD Approach
D-14: Effects of Electrode and Substrate Optimization on Solid Oxide Cell Performance
Design and Sintering of Ceramic-Metal Composites for Extreme Environment Applications
Development of a Li-Corrosion Resistant Coating for Mullite-Cordierite-Based Refractory
Effect of Carbon on the Microstructure and Phase Evolution of High Entropy Dual Phase Ceramics
Effect of SiO2 Content on High-Temperature Phase Transition and Physical Properties in Calcium Aluminate Cement
Fatigue Behavior of Grain Boundaries in High Thermal Conductivity Silicon Nitride Ceramics Evaluated by Microcantilever Bending Test
Finite Element Modeling of Microwave-Assisted Calcination of SOEC Perovskite Precursor Powders
Firing Behavior of 18th Century European Porcelains
Hybrid Microwave Sintering of Electrolytes for SOEC/SOFC Applications
Measurement of Glaze Thermal Expansion via Crazing
Microstructure Development of Electro-Conductive Aluminum Nitride for Sensor Applications
Percolation-Driven Thermal Conductivity Improvement in Pyrolyzed MXene/SiOC Nanocomposites
Reduction Behavior of Mullite/Andalusite-Based Refractories Under Hydrogen Atmosphere and the Effect of Crystalline SiO2 on Mechanical Strength
Small Tests that Make a Big Difference: Correction of the Plastic Size Effect During Micromechanical Testing

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