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Meeting 2026 TMS Annual Meeting & Exhibition
Symposium Advances in Thermo-Mechanical Processing of Refractory Alloys
Presentation Title Investigation of Oxidation Resistance and Hot Deformation Behaviour of Refractory Al0.2 Cr0.2Mo0.2Nb0.2Ta0.2 High-Entropy Alloy Synthesized by Adiabatic Aluminothermic Process
Author(s) Arijit Das, Sanjib Majumdar, Bhaskar Paul, Jugal Kishor Kumhar, Tamanna S R C Murthy, Shubham Kumar
On-Site Speaker (Planned) Arijit Das
Abstract Scope A novel quinary Al0.2 Cr0.2Mo0.2Nb0.2Ta0.2 RHEA was prepared by direct co-reduction of oxide precursors. The exothermic and adiabatic aluminothermic reactions produced a homogeneous BCC phase along with Cr-rich Laves phase (Cr₂Ta type), confirmed via X-ray diffraction (XRD), electron microscopy (SEM) and nanoindentation techniques. The energy density for the thermit process was maintained ~2700-3000 J/gm and confirmed using differential thermal analysis (DTA). The optimum alloy yield obtained was ~70%. The alloy was arc consolidated prior to oxidation and hot deformation studies. Isothermal oxidation at 1100°C-10h resulted in specific weight gains of 8.51 mg/cm² in air and exposure at 1000°C-4h caused 5.52 mg/cm² in steam-air environment. Electron backscattered diffraction (EBSD) and transmission electron microscopy (TEM) analyses after hot deformation between 1200°C-1400°C revealed deformation twinning, stacking faults, and dynamic recrystallization (DRX). The study demonstrates the viability of thermite-based synthesis for scalable RHEA production and emphasizes the role of high-temperature deformation mechanisms in improving structural performance.
Proceedings Inclusion? Planned:
Keywords High-Entropy Alloys, Extraction and Processing, Mechanical Properties

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Breaking the Brittleness Barrier: How Severe Plastic Deformation and Interstitials Affect Plasticity in the TaNbVZrTi RHEA
Controlling Interstitial Impurities to Enable Conventional Manufacturing of Refractory Multi-Principal-Element Alloys
Design of ruthenium containing BCC+B2 refractory alloys and their deformation behavior
Dislocation mechanisms governing the continuous and discontinuous dynamic recrystallization behavior in refractory multi-principal element alloys
Effect of varied thermomechanical processing and heat treatment strategies on MoNbTi
High ductility in as-sintered Mo produced by pressureless sintering
Influence of Combined Thermal and Mechanical Processes on the Recrystallization of Ta–W Alloys
Influence of Thermo-Mechanical Processing on Microstructure and Mechanical Behavior of HfTiZrNbx Alloys
Investigation of microstructure evolution during spin forming of a tantalum-tungsten alloy
Investigation of Oxidation Resistance and Hot Deformation Behaviour of Refractory Al0.2 Cr0.2Mo0.2Nb0.2Ta0.2 High-Entropy Alloy Synthesized by Adiabatic Aluminothermic Process
Ordering induced enhancement of mechanical properties of NbTaTi equiatomic RCCA
Phase Field Modeling of {110} and {112} Slip in W-Re Alloys
The thermal mechanical behavior of refractory alloys at extreme temperatures
Thermomechanical processing of ductile refractory alloys: An industrial perspective
Towards the Production of Bulk Ultra Fined Grained Ductile Tungsten

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