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Meeting MS&T24: Materials Science & Technology
Symposium Preceramic Polymers; Synthesis, Processing, Modeling, and Derived Ceramics
Presentation Title Refractory Ceramics Using High Char Polymers
Author(s) James Sitter, Matthew Laskoski
On-Site Speaker (Planned) James Sitter
Abstract Scope Ultra-high temperature ceramics (UHTCs) demonstrate significant promise in many high-performance applications. However, existing processing typically produce macrocrystalline ceramics that are too brittle and expensive to incorporate into aerospace and military systems. Our approach produces dense, nanocrystalline, monolithic UHTC composites with precursor flexibility that can maximize density while altering hardness, and durability under high temperatures. This process is based on a novel synthesis route using compressed powder mixtures of metal precursors and high char-yielding that yield shaped carbides, nitrides, and borides under mild heat treatment. Incorporation of various metals, fibers, and ceramics into these composites can improve their mechanical, electrical, and thermal properties and adapt them for many emerging applications.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Ceramic Yields of Preceramic Polymer Grafted Nanoparticles using Conventional and Photothermal Heating
D-17: Structure and Properties of Preceramic Polymer Grafted Nanoparticle Monolayers
Developing Ceramic Materials via Preceramic Polymer Chemistry and an Enhanced Understanding of Structure-Property Relationships
Development of Processable Polymer Derived Ultra-High Temperature Ceramics and Composites
Formulation of Preceramic Polymers for Photocuring and 3D Printing of Polymer-Derived Ceramic Lattices
GNPs, NIMs, and UHTC AFPCs: Progress Toward Higher Volume Yielding Preceramics
Improving Mechanical Properties of Polymer-Derived Dense SiC Ceramics with the Integration of 2D MXene
Insights into MXene-SiOC Composite Formation and Properties via Experimental and DFT Studies
Phase and Microstructure Study of Boron-Doped Allylvinylhydridocarbosilane Derived Bulk SiBC Ceramic
Polymer Derived Ceramics: An Evolutionary Algorithm Driven Classical Molecular Dynamics
Preceramic Polymer Grafted Nanoparticle Systems
Refractory Ceramics Using High Char Polymers
Size Effects in Additively Manufactured Polymer-Derived Ceramic Composites
Thermo-Mechanical Effects during the Conversion of Pre-Ceramic Polymers

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