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Meeting 2023 TMS Annual Meeting & Exhibition
Symposium Advanced Materials for Energy Conversion and Storage 2023
Presentation Title Fast-charging Aluminum-chalcogen Batteries Resistant to Dendritic Shorting
Author(s) Donald R. Sadoway
On-Site Speaker (Planned) Donald R. Sadoway
Abstract Scope Announcing a rechargeable aluminum-chalcogen battery operating with a molten salt electrolyte composed of NaCl-KCl-AlCl3. This chemistry is distinguished from other aluminium batteries in the choice of positive elemental chalcogen electrode as opposed to various low-capacity compound formulations, and in the choice of a molten salt electrolyte as opposed to room-temperature ionic liquids. The multi-step conversion pathway between aluminum and chalcogen allows rapid charging at up to 200C while the battery endures hundreds of cycles at very high charging rates without dendrite formation. The cell-level cost of the aluminum-sulfur battery is projected to be less than 1/6 that of current Li-ion technologies. Composed of earth-abundant elements that can be ethically sourced and operating at moderately elevated temperatures just above the boiling point of water, this chemistry has all the requisites of a low-cost, rechargeable, fire-resistant, recyclable battery.
Proceedings Inclusion? Planned:
Keywords Energy Conversion and Storage, Aluminum, Sustainability

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

3D Detailed Modeling Framework of Electrochemo-mechanics Behavior in SiO/Gr Composite Anode for High Energy Density Lithium-ion Battery​
Advanced Na-metal Halide Batteries for Long Duration Energy Storage Applications
Aluminum-Anodes for Metal-Air-Batteries
Analysis of Degradation of (Ni-YSZ) Fuel Electrode during SOEC Operation
Apparent Microstructurally Induced Phase Separation in Porous LiNiMnCoO2 Cathodes
Application of Electrodeposited Zinc Thin Film to Anode of Zn-Ni Secondary Battery for Thousands of Charge-Discharge Cycles
Assembled MXene/Carbon Nanotube Electrodes with Anomalous Electrochemical Response
Atomistic Simulations of Reaction Kinetics at Electrochemical Interface
Bioinspired Hydrogen Electrolyzer
Cathode Materials Recycling, Regeneration, and Reuse
Challenges of ASSB development for Future Electric Vehicle Application
Correlating Microstructural Evolution in Reversible Solid Oxide Electrochemical Cells to their Performance
Corrosion Resistant SiOCN Coatings on Steel with Repair Capability
D-10: Rapid Thermal Buffering via Sorption based Energy Storage Materials
D-11: Reversible Aqueous Formate-based Na-CO2 Battery Enabled through Earth-abundant Nanoporous Metals
D-12: Spectroscopic Investigation of Long Cycling Al-ion Batteries Enabled by Ionic Liquid Electrolytes with Organic Additives
D-13: Surface Engineered TiO2 Nanostructures as Effective Cathode Host Materials in Li-S Batteries
D-14: Surface Oxidation of MNiSn (M=Ti, Zr, Hf) Half-Heusler Alloys
D-1: Computational Study for Structural Evolution and Ion Migration in Li-Mn-rich Layered Electrode
D-2: Electrochemical Hydrogenation of Furfural to 2-Methylfuran under Mild pH Environment over Silver/Nanoporous Copper Catalyst
D-3: Enhanced Reversibility in Calcium Chloride Hexahydrate with Nucleation Agents for Thermal Energy Storage Applications
D-46: Fabrication of the Seamless Stainless Tube for Hydrogen Refueling Stations
D-4: In-situ and Ex-situ Surface Engineering, Processing, and Characterization of PLA-based Biocompatible Composites Using Micro-plasma-based Techniques
D-5: Investigation Mechanical Process of New Alloy Electrode Using All Solid State Battery
D-6: Lithium-Ion Battery Silicon Anodes: Reducing Mechanical Degradation through Morphological Design
D-7: Mechanical Testing of Novel Chromium Superalloys Strengthened by Intermetallic Precipitates
D-8: Non-destructive Evaluation of Defects in Composite Pressure Vessels for Hydrogen Storage
D-9: Novel Thermal Barrier Coatings Stable up to 1700°C
Designing Electrode Architectures Across Length Scales
Development of High Energy-density and High-power Density Lithium-ion Capacitors Based on MnO2/GO Nanocomposite Electrode for Energy Storage System
Development of Novel Green Manufacturing Technologies for Fabricating Functional Materials
Dielectrics, Solid Electrolytes, and Ferroelectrics: What Makes a Good Insulator Layer in Energy Harvesting and Storage Cells Good?
Electrochemical Systems for Global Net-Zero and Zero Carbon Electricity Infrastructure
Elucidating the Governing Forces Behind Chemo-Mechanical Instabilities in Electrodes for Alkali Metal-ion Batteries
Enabling High-energy-density Cathodes by Coupling Electrochemistry and Mechanics across Length Scales
Experimental Simulation of the Erosive-Corrosive Wear and Shear Rate Dependence of an Iron and Molten Al-Si Thermal Storage System
Fabrication and Electrochemical Characterization of Si-C Hybrid Nanocomposites for High-performance Li Ion Batteries
Fast-charging Aluminum-chalcogen Batteries Resistant to Dendritic Shorting
First-Principles Studies of Metal Nanoparticles on Substrates for Advanced Manufacturing Applications
Grain Boundary Metal-Insulator Transitions in Polycrystalline LiCoO2
High Performance Reversible Solid Oxide Fuel Cells (RSOCs) Based on Ruddlesden-Popper Oxygen Electrodes for Grid Scale Energy Storage
High Recycled Content Aluminum Alloy Current Collector for Lithium-Ion Batteries
How Safe Are Solid-State Batteries? An Exploration of Heat Release
Hybrid Halide Solid Electrolytes and Bottom-up Cell Assembly Enable High Voltage Solid-state Lithium Batteries
In-situ Mitigation of Chromium Poisoning in SOFC Air Electrodes
Large-Scale Phase-field Modeling of Lithium Dendrite Growth
Mechanistic Analysis of Interface Stability in Solid-State Batteries
Micro Plasma-based Surface Modification of Biocompatible Polymers and Composites towards the Modification of Surface Properties for Biomedical Applications
Mitigate Plating in Graphite Using Electrode Microstructure Simulations
Modelling and Optimization of Nanofiber-based Triboelectric Nanogenerators
Multiphysics Models for Understanding and Enhancing Cycle and Calendar Life of Silicon-rich Lithium-ion Batteries
New Compounds with Distinct Porous Morphology
New Family of Interstitial Oxygen Ion Conductor Discovered by High-Throughput Computational Screening
On the Specific Capacity and Cycle Stability of Si Anodes: Effects of Charge/Discharge Protocol
Operando Degradation Analytics Using 3ε Toolbox
Opportunities and Challenges for In Situ Synchrotron Characterization of All Solid State Batteries
Physics-based Understanding of Heterogeneous Nucleation during Lithium Electrodeposition
Probing the Role of SEI Heterogeneity on Sodium Plating and Stripping
Protective Coatings on Porous Interconnects for SOFC Applications
Rate, Size, and Temperature Effects in Alkali Metal Anodes
Salt Hydrate Eutectics: Expanding the Palette of Phase Change Materials for Thermal Energy Storage
SolidPAC: A Design Tool for Solid-state Batteries
Structural Integrity at Elevated Temperature Assessment of Solid Particles for Concentrated Solar Power Systems Using ICME Approach
Study of the Efficacy of a Perovskite Sensor-Based Non-Invasive Glucose Monitoring System Using Infrared Light Intensity Correlations: Towards the Development of Measurement Metrics Using Data Analytics
Sulfur and Chromium Poisoning Mechanism of Lanthanum Nickelate Cathode Material: A Thermodynamic and Experimental Study
Synthesis, Characterization and Determination of Electrical Properties of Potassium Jarosite Powders
The Compatibility of Metallic Phase Change Materials and Alumina Coating on Steel Housing Material
The Energy Saving Potential of Thermo-responsive Desiccants for Air Dehumidification
Thermal and Rheological Properties of Sodium Sulfate Decahydrate Phase Change Materials with various Thickening and Stabilization Mechanisms
Towards Fracture-free Bulk Silicon Anodes for Lithium-ion Batteries
Triple-cation Perovskite Photoabsorbers and Solar Cells
Ultra-Thick Electrodes for High Energy and Power Density Lithium-ion Batteries
Understanding Improved Alkali Metal Plating of Sodium Compared to Lithium via 2DIR characterization and MD Simulation of Weaker Solvation Behavior for High Energy Battery Systems
Understanding Reactive Metals for Future Batteries - Lithium vs. Sodium

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