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Meeting 2017 TMS Annual Meeting & Exhibition
Symposium Energy Materials 2017: Materials for Energy Conversion with Emphasis on SOFC
Presentation Title Poisoning Mechanism and Performance Degradation at SOFC Cathode/Electrolyte Interfaces
Author(s) Teruhisa Horita, Masahiro Ishiyama, Katherine Develos-Bagarinao, Haruo Kishimoto, Katsuhiko Yamaji
On-Site Speaker (Planned) Teruhisa Horita
Abstract Scope Poisoning is one of the critical issues to commercialize the durable and long-term stable SOFC systems. So far, Cr- and S- poisoning are the main impurities that affect the cathode performances. Especially at the (La,Sr)(Co,Fe)O3/CeO2/ZrO2 interfaces, a significant amount of SrCrO4 and SrSO4 are formed at the grain surfaces or triple phase boundaries which affects the reaction rates for oxygen reduction as well as O2- diffusion rates inside the (La,Sr)(Co,Fe)O3 due to loss of oxygen vacancies. Also, Sr diffusion through CeO2 and formation of SrZrO3 was observed at the CeO2/ZrO2. In this presentation, poisoning mechanisms are reviewed and related performance electrochemical degradation are discussed. The prospect for the life time estimation is also discussed.
Proceedings Inclusion? Planned: Stand-alone book in which only your symposium’s papers would appear (indicate title in comments section below)


Analysis of the Effects of Chromium Poisoning on LSM-based Cathode Using Polarization Modeling and Impedance Measurements
C-10: Effect of Sn on the Microstructure and Mechanical Properties of AM90 Extruded Alloy
C-9: Composition Effects on the Characteristics of Glass Sealants for Intermediate Temperature Solid Oxide Fuel Cell Applications
Chromium Impurity Effects on SOFC Cathodes Using Half-cell Measurements
Development of Solid Oxide Fuel Cell Residential CHP System
Effect of Strontium Content and Strain on Surface Segregation in LSCF
Electrophoretically Deposited Copper Manganese Spinel Coatings for Interconnections in Solid Oxide Fuel Cells
Enhanced Performance of Doped Ceria Electrolyte by the Addition of Barium Carbonate in Solid Oxide Fuel Cells
Fabrication and Operation of a 600W Anode-supported Tubular SOFC Stack
Investigation on Cathode Interlayer and Electrolyte for Improving Electric Power Efficiency of SOFCs
Low Temperature RAA Process for SOFC Stacks
Mitigation of Chromium Poisoning in Solid Oxide Fuel Cells
Modified SOFC Cermet Anodes for Improved Catalysis at High Fuel Utilization
New Materials for Solid Oxide Fuel Cells
Oxygen Reduction Reaction at the Cathode of Solid Oxide Fuel Cell Enhanced with Oxide Particles
Oxygen Reduction Reaction Mechanisms on Ruddlesden-Popper Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells
Phase Field Modelling of Microstructure and Conductivity Evolution of SOFC Electrodes
Plasma Sprayed Protective Coatings on Metallic SOFC Interconnects: Interplay between Processing and Performance
Poisoning Mechanism and Performance Degradation at SOFC Cathode/Electrolyte Interfaces
Reactive Synthesis of Spinel Contact Layers with Metallic Precursor Powders
Synthesis and Characterisation of Perovskite Type Anode Material and Its Tape Casting for IT-SOFC Application

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