About this Abstract |
Meeting |
2016 TMS Annual Meeting & Exhibition
|
Symposium
|
Recent Developments in Biological, Structural and Functional Thin Films and Coatings
|
Presentation Title |
Effect of Post-Heat Treatment on the Electrochemical Performance of Sandwich Structured Cu/Sn/Cu Electrode |
Author(s) |
Burcin Bilici, Deniz Billur Polat, Ozgul Keles |
On-Site Speaker (Planned) |
Burcin Bilici |
Abstract Scope |
In this work, we have produced Cu/Sn/Cu sandwich structured film by electrodeposition method, to be used as a negative electrode for rechargeable lithium ion battery. To promote the interaction between Cu-Sn-Cu layers, an additional post-heat treatment (2000C, 48h under vacuum atmosphere) has been applied to the coating. The galvanostatic test results prove that morphological changes and CuxSi intermetallics formation in the film as a result of heat treatment process promote the capacity retention of the electrode. After 30 cycle, the capacities of the Cu/Sn/Cu electrodes with and without heat treatments are 230 mAh g-1, 100 mAh g-1 respectively. This demonstrates that the post-heat treatment process improves cycle performance of the electrode. |
Proceedings Inclusion? |
Planned: A print-only volume |