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Meeting 2020 TMS Annual Meeting & Exhibition
Symposium Process Metallurgy and Electrochemistry of Molten Salts, Liquid Metal Batteries, and Extra-terrestrial Materials Processing: An EPD Symposium in Honor of Don Sadoway
Presentation Title Electrodeposition of Titanium from Alkali Fluoride-Chloride Molten Salts
Author(s) Yutaro Norikawa, Makoto Unoki, Kouji Yasuda, Koma Numata, Mitsuyasu Ogawa, Masatoshi Majima, Toshiyuki Nohira
On-Site Speaker (Planned) Toshiyuki Nohira
Abstract Scope Electroplating is a promising approach to utilize the superior properties of titanium, such as corrosion resistance and biocompatibility. Even complex-shaped materials can be coated by electroplating. Generally, compact and smooth Ti films were obtained from fluoride melts such as LiF–NaF–KF. However, one of the problems using fluoride-based molten salts was the difficulty in removing the salt adhered to the deposited Ti due to low solubility of LiF and NaF in water. Recently, we have proposed a new electrodepositon process of Ti using water-soluble KF–KCl molten salts. This paper presents the electrodeposition of Ti and the electrochemical behavior of Ti(III) ions in molten KF–KCl. Moreover, comparison with the results obtained in LiF–LiCl will be given to discuss the effect of cations on the electrochemical behavior of Ti ions.
Proceedings Inclusion? Planned: Supplemental Proceedings volume

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Application of Electronically Mediated Metallothermic Reductions in Molten Salts to Nuclear Materials
Are the Metallic Iron Inclusions Exist on the Surface of the Moon?
Better Living through Electrochemistry: A Career of Scientific Solutions and Pragmatism
Development of a New Electrodeposition Process based on Liquid Metal Electrochemical Technologies in Molten Salt Electrolytes
Electrochemical Processing under Extreme Conditions
Electrodeposition of Titanium from Alkali Fluoride-Chloride Molten Salts
Extraction of Magnesium from Aluminum Scrap Melts by Molten Salt Electrorefining
Fluid Mechanics of Liquid Metal Batteries: Overview and Outlook
Getting the Most from Models in High-Temperature Materials Processing
History of Inventions and Innovations for Aluminum Production
Hybrid Processes in Refining of Silicon
Innovative Ways to Chemically Process Rare-earth Waste Materials
Insights into the Oxidation Behavior of Cr1−xFex Anodes for Molten Oxide Electrolysis
Know Your Audience: Four Decades of Educational Innovation
Liquid Metal Batteries: From Concept to Commercialization
Lithium Metal Battery for Future Energy Storage
Molten Oxide Electrolysis for the Production of Ferroalloys and Steel
Open-circuit Explosions and Basement Thermite Fires Threaten Aluminum Potlines
Recovery of Metal Values from Wastes
Study of Electrode Performance Improvement with Infiltration of Electronic and Mixed-conducting Nanoparticles Employing Electrochemical Impedance Spectroscopy and I-V Measurements
Study on Electronically Mediated Reaction (EMR), and What I Learned from Professor Sadoway
The Application of the FFG Molten Salt Cycle on the Separation of the Refractory Metals
Thermodynamic and Kinetic Modelling of Molten Oxide Electrolysis Cells
Thermodynamics of Electrode Reactions for Energy Storage, Separation, and Corrosion
Titanium Extraction from Industrial Raw Material to Metal through Carbothermic Reduction and Molten Salts Electrolysis
Trends and Challenges for Electrowinning of Aluminium and Magnesium from Molten Salt Electrolytes

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