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Meeting Materials Science & Technology 2011
Symposium Advanced Protective Coatings for Refractory Metals and Alloys
Presentation Title Phase Formation and Oxidation Resistance of Mo-Si-B Alloys
Author(s) Kyosuke Yoshimi, Seong-Ho Ha, Kouichi Maruyama, Naoyuki Nomura, Shuji Hanada
On-Site Speaker (Planned) Kyosuke Yoshimi
Abstract Scope In this paper, our achievement on the phase formation and stability and oxidation resistance of Mo-rich Mo-Si-B alloys is reviewed. In the Mo-rich side of the Mo-Si-B ternary system, there are some eutectic reaction points in the liquidus projection. The solidification pathways suggest the possibility for amorphous and/or nanocrystalline structure formation during rapid solidification. Mo-Si-B amorphous phase and Mo3Si-Mo5Si3-Mo5SiB2 nanocrystalline structure formation was confirmed in the entire coating produced by low-pressure plasma spraying using Mo3Si-Mo5Si3-Mo5SiB2 multiphase powder, by which coating materials are rapidly solidified on substrate. The oxidation resistance of the plasma-sprayed coating was much better than that of the bulk sample produced by arc-melting and annealing. Therefore, the oxidation resistance of Mo-Si-B coatings is improvable by rapid solidification processes through amorphous phase and nanocrystalline structure formation relevant to the eutectic reactions.
Proceedings Inclusion? Definite: A CD-only volume

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Balancing the Properties of Structural Mo-Borosilicide Alloys for Ultra-High Temperature Applications
Coating Strategies to Improve the Oxidation Resistance of Bcc-Mo-Based Mo-Si-B Alloys
Deposition of Silicide Based Protective Coatings on C-103 Niobium Alloy with Different Surface Microstructures
Design and Synthesis of Al-Doped MoSiB Coatings
Development of Bond Coatings for Titanium Aluminide Intermetallics
Effect of Al on the Oxidation Resistance of Alloys from Nb-Si-Cr System
Formation of MoSi2 and Al Doped MoSi2 Coatings on Molybdenum Base TZM Alloy
High Temperature Oxidation Resistant Mo-Si-B Alloys and Coatings
Influence of Minor Element Addition on the Oxidation Performance of Mo-Si-B Alloys
Interaction between CMAS and Mo-Si-B Coatings
Low Temperature Oxidation Behavior of Niobium Alloys
Mo-Mo2B-Silicate Composites, Mechanics and Oxidation
Multimillion Atom Molecular Dynamics Simulations of Reactive Nanosystems
Oxidation Resistance of Nb Based Alloys from 700 to 1400oC in Air
Oxidation Resistant Mo-Si-B Coatings on Tungsten for Ultra High Temperature Environmental Protection
Phase Formation and Oxidation Resistance of Mo-Si-B Alloys
Protective Coatings for Molybdenum – Industrial Processing and Applications
ReaxFF Reactive Force Field for Molecular Dynamics Simulations of Niobium Oxidation
Structural Formation and Oxidation Resistance of Si-Al-Y Co-Deposition Coatings on Nb-Ti-Si Based Multicomponent Ultrahigh Temperature Alloy
Synthesis and Performance of Platinum Group Metals Modified βNiAl Coatings for Enhanced Oxidation Stability of Mo-Based Alloys
The Potential of Nb-Si Alloys for Advanced Turbine Applications
Thermal Cycling Behavior of Gd2Zr2O7 Based Thermal Barrier Coatings
Water Vapor Effects on the Volatility of Borides, Silicides and Aluminides for Refractory Alloy Coatings

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