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Meeting 2016 TMS Annual Meeting & Exhibition
Symposium Phase Transformations in Multi-component Systems: An MPMD Symposium Honoring Gary R. Purdy
Presentation Title Pt-Rh Failure through Distinct Phosphorus Diffusion Mechanisms
Author(s) Anna Nakano, James Bennett, Jinichiro Nakano
On-Site Speaker (Planned) Jinichiro Nakano
Abstract Scope Certain gaseous species; including arsenic, phosphorous, and sulfur; would cause Pt-Rh thermocouples to fail if used in reducing atmospheres at elevated temperatures. Unlike sulfur and arsenic, sensor degradation by phosphorous has not been well known. In this work, Pt-Rhx alloys were interacted with gaseous phosphorous oxide to study the failure mechanism in various oxygen partial pressures. The analysis revealed material degradation was caused by a combination of 1) Pt liquidus lowering and 2) intermediate phase formation at grain boundaries or gas/solid interfaces through two distinct phosphorous diffusion routes dependent on Rh alloying content: intergranular for low Rh alloys and intragranular for high Rh content. A critical chemical border between intergranular and intragranular was also investigated using a diffusion couple technique between pure Pt and Pt-30wt.% Rh. The general failure mechanisms of the Pt-Rh thermocouples by phosphorous under conditions studied will be discussed.
Proceedings Inclusion? Planned: A print-only volume

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

An In-situ TEM Investigation of a Reverse Martensite Transformation in an Fe-20Ni-5.4Mn Alloy
An Integrated Model for Microstructure Development in the Heat Affected Zone of Linepipe Steels
Analysis of Mo Effect on the Kinetics of Ferrite and Bainitic Ferrite Formation
Analyzing Internal Interfaces Chemistry down to the Atomic Scale
Atomistic Modeling and Experiments of Spinodal Decompostion in Fe-Ni-C Martensite
Atomistic Simulations of the Interaction of Alloying Elements with Interfaces
Austenite Reversion during Intercritical Annealing in a Medium-Mn Steel: Simulations and Experiments
Carbon Enrichment in Austenite during Ferrite and Bainite Transformations in Fe-Mn-C Based Alloys
Cellular Precipitation in Cu-3% Ti
Diffusional Phase Transformations in Multicomponent Single-Phase/Two-Phase Diffusion couples
Effect of Boron on the Bainitic Transformation Kinetics after Ausforming Process
Effects of Internal Oxidation on Microstructure in Ni Alloy 600
Evolution of Mn/Cr Composition Gradients in Cementite during Annealing of DP Steels
Formation of Widmanstätten Ferrite by the Dynamic Transformation of Austenite at Temperatures Well above the Ae3
Grain Boundary Segregation in Phase Separating Nanocrystalline Alloys: The Role of Competing Processes on Microstructure Evolution
Grain Boundary Segregation of Nb in Fe-30%Mn Austenite Steels
Hidden Pathway and Defects Generation during Structural Phase Transformations
High Throughput Screening of Phase Transformation in Multi-component Ti Alloys: Kinetic Diffusion Multiple
In-situ Observation of Austenite Growth in Very Low Carbon Fe-Ni and Mn Alloys
In Situ Investigations of Partitioning Mechanisms in Q&P Steels by Synchrotron Diffraction Experiments
Incomplete Bainite Transformation in Fe-0.4C-3Si Alloy
Kinetics and Mechanism of Austenite Isothermal Transformation in Carbonitrided Low-alloy Steel
Kinetics of Cellular Growth and Coarsening in Aged U-Nb Alloys
Kinetics of Decomposition in Fe-Cr Alloys and Refractory Carbides
Modelling the Condition of Upper and Lower Bainite Formation
Molecular Dynamics Simulation of fcc/bcc Interface Migration in Pure Iron
New Insights into Alloying Elements Interaction with Migrating α-ferrite/γ-austenite Interface in Fe-C-Mn System
On the Feathery Structure of Bainite
On the Question of Solute Atom Trajectories during Dynamic Segregation
On the Roles of Dislocations in Austenite Reversion from Martensite
Particularities of Kinetics of Austenite Decomposition above and below Martensite-Start Temperature in the Carbide Free Low Alloyed Steel
Pt-Rh Failure through Distinct Phosphorus Diffusion Mechanisms
Quenching and Partitioning of a Ductile Cast Iron
Reversed Austenite Transformation in Medium Manganese Steels
Reversion of Austenite from Martensitic Fe-2Mn-1.5Si-0.3C Alloy during Continuous Heating Process
Segregation and Nanoscale Precipitation in Multi-component Fe-Cu Based Steel
Shortening a CALPHAD Approach by Understanding Parameter Relationships
Solute Drag in a 40 Years Perspective
Solute Interactions at the Ferrite-Austenite Interphase Boundary
T-1: Modeling of Acicular Ferrite Growth
T-2: Phase Equilibria of Vanadium Bearing Slags
T-3: Solid State Reaction of Nd2Fe14B and Carbon
Tempering Behaviour of a Quenched Microalloyed Pipeline Steel
The Effect of C and N on the Cyclic Partial Phase Transformation Behaviour in an Mn Containing Steel
Towards a Unified Analysis of Migrating Austenite/Ferrite Interfaces in Steels
Who Cares About Phase Transformations? A Tribute to Gary Purdy

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