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Meeting Materials Science & Technology 2011
Symposium Advanced Protective Coatings for Refractory Metals and Alloys
Presentation Title Coating Strategies to Improve the Oxidation Resistance of Bcc-Mo-Based Mo-Si-B Alloys
Author(s) Mufit Akinc, Matthew Kramer, Pratik Ray, Zhihong Tang
On-Site Speaker (Planned) Mufit Akinc
Abstract Scope Mo-based Mo-Si-B alloys have promising high temperature mechanical properties. In particular, the Mo+T2(Mo5SiB2)-based alloys have excellent resistance to fracture, with toughness values approaching 20 MPa•m½ for a continuous β-Mo matrix material. However, a fundamental limitation of these alloys is their poor oxidation resistance. A consensus is emerging to protect the Mo-based alloys with an oxidation resistant coating such as the T1-based alloy. Two different coating processes were investigated. First, the T1-based alloy was plasma-sprayed onto Mo substrates to determine the feasibility of protecting the Mo+T2(Mo5SiB2)-based alloys. The second coating strategy involved siliconizing the surface of the Mo based alloy by the halide activated pack-cementation (HAPC) process. A critical problem with coating materials is the formation of brittle intermetallic phases like the A15 during subsequent heat-treatments. Our studies on Nb and W additions indicate it might be possible to destabilize this phases in order to improve the alloys mechanical properties.
Proceedings Inclusion? Definite: A CD-only volume

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Balancing the Properties of Structural Mo-Borosilicide Alloys for Ultra-High Temperature Applications
Coating Strategies to Improve the Oxidation Resistance of Bcc-Mo-Based Mo-Si-B Alloys
Deposition of Silicide Based Protective Coatings on C-103 Niobium Alloy with Different Surface Microstructures
Design and Synthesis of Al-Doped MoSiB Coatings
Development of Bond Coatings for Titanium Aluminide Intermetallics
Effect of Al on the Oxidation Resistance of Alloys from Nb-Si-Cr System
Formation of MoSi2 and Al Doped MoSi2 Coatings on Molybdenum Base TZM Alloy
High Temperature Oxidation Resistant Mo-Si-B Alloys and Coatings
Influence of Minor Element Addition on the Oxidation Performance of Mo-Si-B Alloys
Interaction between CMAS and Mo-Si-B Coatings
Low Temperature Oxidation Behavior of Niobium Alloys
Mo-Mo2B-Silicate Composites, Mechanics and Oxidation
Multimillion Atom Molecular Dynamics Simulations of Reactive Nanosystems
Oxidation Resistance of Nb Based Alloys from 700 to 1400oC in Air
Oxidation Resistant Mo-Si-B Coatings on Tungsten for Ultra High Temperature Environmental Protection
Phase Formation and Oxidation Resistance of Mo-Si-B Alloys
Protective Coatings for Molybdenum – Industrial Processing and Applications
ReaxFF Reactive Force Field for Molecular Dynamics Simulations of Niobium Oxidation
Structural Formation and Oxidation Resistance of Si-Al-Y Co-Deposition Coatings on Nb-Ti-Si Based Multicomponent Ultrahigh Temperature Alloy
Synthesis and Performance of Platinum Group Metals Modified βNiAl Coatings for Enhanced Oxidation Stability of Mo-Based Alloys
The Potential of Nb-Si Alloys for Advanced Turbine Applications
Thermal Cycling Behavior of Gd2Zr2O7 Based Thermal Barrier Coatings
Water Vapor Effects on the Volatility of Borides, Silicides and Aluminides for Refractory Alloy Coatings

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