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Meeting Materials Science & Technology 2011
Symposium Solution-Based Processing for Ceramic Materials
Presentation Title Investigation of Solution Combustion Synthesis and Precipitation Synthesis Conditions on TiO2 and ZnO Nanopowder Characteristics
Author(s) James P. Kelly, Olivia A. Graeve
On-Site Speaker (Planned) James P. Kelly
Abstract Scope TiO<sub>2</sub> and ZnO nanopowders have interesting electrical properties leading to their potential use in energy harvesting applications. Solution combustion synthesis (SCS), which most commonly uses metal nitrate precursors as an oxidizer source, is a synthesis technique that can result in fine powders. The lack of a stable titanium nitrate precursor has inspired us to investigate inexpensive and easy-to-handle metal complexes as fuel sources in the SCS process. SCS was performed using various amounts of either dihydroxybis(ammonium lactato)titanium complex or zinc citrate dihydrate complex as the fuel source and ammonium nitrate as the oxidizer. Direct precipitation of the respective oxides from these precursors is also attempted by use of dissolution and condensation reactions. Reactant concentrations as well as calcining temperature and time were studied. X-ray diffraction, dynamic light scattering, and thermogravimetric analysis were used to evaluate the phases, crystallite sizes, particle sizes, and contamination of the powders.
Proceedings Inclusion? Undecided

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Bottom-Up Evolution of BaTiO3 and SrTiO3 Nanocubes in Ordering Structure
Chemical Solution Deposition of Lead Free (K0.5Na0.5)NbO3 Piezoelectric Thin Films
Construction of Highly Ordered Nanofilms through Langmuir-Blodgett Deposition of Oxide Nanosheets
Curing Behavior in Photopolymerizable Ceramic Suspensions
Direct Patterning of Nano-Structured Ceramics from Solution: Differences from Conventional Printing and /or Lithographic Methods
Electrochemical Deposition of Nano Tuberous TiO2 and Their Application
Flexible Ceramic Nanofibermats for High Efficiency Particulate Air Filtration in Lunar Missions
Functional Oxide Thin Films for Energy Efficient Devices by Chemical Solution Deposition
Investigation of Solution Combustion Synthesis and Precipitation Synthesis Conditions on TiO2 and ZnO Nanopowder Characteristics
Low Temperature Ferroelectric Thin Films: The Potential of the Novel Technology of Photochemical Solution Deposition
Novel Catalytic Phenomena of Mesoporous Silica Composites Controlled by Sol-Gel Processing
Polymeric Precursor Synthesis of Ce(1-x)BixO(2-x/2) Powders Assisted by Sonic Cavitation
Solution-Based Processing of Dielectric and Ferroelectric Nanostructured Ceramic Oxides
Solution Processing of Perovskite Thin Films for Optimized Functional Properties
Solution Synthesis of Perovskites and Complex Transition Metal Oxides
Spin Sprayed Nickel Copper Manganite Films for Thermal Imaging
Study of Reverse Micelle Nanoreactors for the Controlled Preparation of Zirconium Hydroxide Precipitates
Synthesis and Characterization of Phase–Change Nanowires Confined in Periodic Mesoporous Silica
Tailor-Made Ceramic Nanocrystals by Organic-Ligand-Assisted Hydrothermal Synthesis
Ultrasonically Assisted Synthesis of A2ZryTi2-yO7 (A = Y, Dy, Gd) Pyrochlore and Fluorite-Type Solid Solutions

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