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Meeting Materials Science & Technology 2011
Symposium Advanced Protective Coatings for Refractory Metals and Alloys
Presentation Title Design and Synthesis of Al-Doped MoSiB Coatings
Author(s) Ridwan Sakidja, Dylan Liebl, John H Perepezko
On-Site Speaker (Planned) Ridwan Sakidja
Abstract Scope Mo-Si-B based coatings have recently received increased interest due to their superior high-temperature oxidation resistance. One of the phase constituents, MoSi2, however is subject to accelerated oxidation ("pesting") at low temperature. To further enhance the oxidation resistance particularly at low to moderate temperature, we synthesized Al-doped Mo-Si-B based coatings by substituting part of Si with Al source powders during the Si+B co-pack cementation process. A simultaneous deposition of Al, Si and B using the appropriate activators is feasible due to the favorable gaseous thermodynamics and growth kinetics conditions. The simultaneous deposition also results in a number of new high-temperature oxidation resistant coatings such as a mixed coating comprised of B-doped silicides and aluminides. The support from ONR (N00014-10-1-0913)is gratefully acknowledged.
Proceedings Inclusion? Definite: A CD-only volume

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Balancing the Properties of Structural Mo-Borosilicide Alloys for Ultra-High Temperature Applications
Coating Strategies to Improve the Oxidation Resistance of Bcc-Mo-Based Mo-Si-B Alloys
Deposition of Silicide Based Protective Coatings on C-103 Niobium Alloy with Different Surface Microstructures
Design and Synthesis of Al-Doped MoSiB Coatings
Development of Bond Coatings for Titanium Aluminide Intermetallics
Effect of Al on the Oxidation Resistance of Alloys from Nb-Si-Cr System
Formation of MoSi2 and Al Doped MoSi2 Coatings on Molybdenum Base TZM Alloy
High Temperature Oxidation Resistant Mo-Si-B Alloys and Coatings
Influence of Minor Element Addition on the Oxidation Performance of Mo-Si-B Alloys
Interaction between CMAS and Mo-Si-B Coatings
Low Temperature Oxidation Behavior of Niobium Alloys
Mo-Mo2B-Silicate Composites, Mechanics and Oxidation
Multimillion Atom Molecular Dynamics Simulations of Reactive Nanosystems
Oxidation Resistance of Nb Based Alloys from 700 to 1400oC in Air
Oxidation Resistant Mo-Si-B Coatings on Tungsten for Ultra High Temperature Environmental Protection
Phase Formation and Oxidation Resistance of Mo-Si-B Alloys
Protective Coatings for Molybdenum – Industrial Processing and Applications
ReaxFF Reactive Force Field for Molecular Dynamics Simulations of Niobium Oxidation
Structural Formation and Oxidation Resistance of Si-Al-Y Co-Deposition Coatings on Nb-Ti-Si Based Multicomponent Ultrahigh Temperature Alloy
Synthesis and Performance of Platinum Group Metals Modified βNiAl Coatings for Enhanced Oxidation Stability of Mo-Based Alloys
The Potential of Nb-Si Alloys for Advanced Turbine Applications
Thermal Cycling Behavior of Gd2Zr2O7 Based Thermal Barrier Coatings
Water Vapor Effects on the Volatility of Borides, Silicides and Aluminides for Refractory Alloy Coatings

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