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Meeting 2017 TMS Annual Meeting & Exhibition
Symposium Energy Materials 2017: Materials for Energy Conversion with Emphasis on SOFC
Presentation Title Effect of Strontium Content and Strain on Surface Segregation in LSCF
Author(s) Yang Yu, Karl Ludwig, Srikanth Gopalan, Uday Pal,
On-Site Speaker (Planned)
Abstract Scope Strontium doped lanthanum cobalt ferrite (LSCF) is a widely used cathode material in solid oxide fuel cells (SOFC). However, LSCF can have long-term stability issues that can adversely affect electrochemical performance. In this study, heteroepitaxial thin films of La1-x SrxCo0.2Fe0.8O3-δ with varying Sr content (x = 0.4, 0.3, 0.2) were deposited on single crystal NdGaO3, SrTiO3 and GdScO3 substrates by pulsed laser deposition, leading to different strains in the films. The extent of Sr-rich precipitate formation at the film surface was quantified using the synchrotron-based total reflection X-ray fluorescence (TXRF), and atomic force microscopy (AFM). The microstructure and the bonding of the surface Sr-rich phases were investigated by scanning/transmission electron microscopy (S/TEM) and hard x-ray photoelectron spectroscopy (HAXPES), respectively. The strain in the thin films was measured by high-resolution x-ray diffraction (HRXRD). The effect of the strontium content and strain on the extent of surface phase formation will be discussed.
Proceedings Inclusion? Planned: Stand-alone book in which only your symposium’s papers would appear (indicate title in comments section below)


Analysis of the Effects of Chromium Poisoning on LSM-based Cathode Using Polarization Modeling and Impedance Measurements
C-10: Effect of Sn on the Microstructure and Mechanical Properties of AM90 Extruded Alloy
C-9: Composition Effects on the Characteristics of Glass Sealants for Intermediate Temperature Solid Oxide Fuel Cell Applications
Chromium Impurity Effects on SOFC Cathodes Using Half-cell Measurements
Development of Solid Oxide Fuel Cell Residential CHP System
Effect of Strontium Content and Strain on Surface Segregation in LSCF
Electrophoretically Deposited Copper Manganese Spinel Coatings for Interconnections in Solid Oxide Fuel Cells
Enhanced Performance of Doped Ceria Electrolyte by the Addition of Barium Carbonate in Solid Oxide Fuel Cells
Fabrication and Operation of a 600W Anode-supported Tubular SOFC Stack
Investigation on Cathode Interlayer and Electrolyte for Improving Electric Power Efficiency of SOFCs
Low Temperature RAA Process for SOFC Stacks
Mitigation of Chromium Poisoning in Solid Oxide Fuel Cells
Modified SOFC Cermet Anodes for Improved Catalysis at High Fuel Utilization
New Materials for Solid Oxide Fuel Cells
Oxygen Reduction Reaction at the Cathode of Solid Oxide Fuel Cell Enhanced with Oxide Particles
Oxygen Reduction Reaction Mechanisms on Ruddlesden-Popper Cathodes for Intermediate-Temperature Solid Oxide Fuel Cells
Phase Field Modelling of Microstructure and Conductivity Evolution of SOFC Electrodes
Plasma Sprayed Protective Coatings on Metallic SOFC Interconnects: Interplay between Processing and Performance
Poisoning Mechanism and Performance Degradation at SOFC Cathode/Electrolyte Interfaces
Reactive Synthesis of Spinel Contact Layers with Metallic Precursor Powders
Synthesis and Characterisation of Perovskite Type Anode Material and Its Tape Casting for IT-SOFC Application

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