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Meeting MS&T21: Materials Science & Technology
Symposium Synthesis, Characterization, Modeling and Applications of Functional Porous Materials
Presentation Title Microporous Copper Spheres: Processing, Morphology, and Application
Author(s) Braden Jones, Beck Boan, Mark Atwater
On-Site Speaker (Planned) Braden Jones
Abstract Scope Porous metals have many applications including lightweight structural components and functional enhancement. Here we combine first-time results in producing, characterizing, and applying foamable millimeter-scale Cu spheres. When a Cu-CuO mixture is ball milled under the appropriate conditions, the resulting product is comprised of copper spheres with selectable size. Annealing in the presence of argon and/or hydrogen at temperatures greater than 600 °C results in porosity within the spheres, and when spheres are compacted together, a hierarchical pore structure results. The strength of these sintered structures can be enhanced by transient liquid-phase sintering. This is accomplished by using the Cu spheres as the milling media to ball mill a lower melting temperature metal, such as aluminum. This results in aluminum coated Cu spheres that can be processed identically to pure Cu through annealing and sintering, but which exhibits higher strength. The strategies, findings, and implications for commercial development will be discussed.

OTHER PAPERS PLANNED FOR THIS SYMPOSIUM

Chemical-aided Synthesis of Anorthite-sodalite-afghanite Porous Ceramics from Granite-clay-plantain Peel Mix
Functional Applications of Porosity in Complex Crystals
Hydrogen-bonded Organic Framework Materials for Gas Separation
Integrated Multi-characterization Approach to Understand Pore Size Distributions in Natural Porous Materials
Layer-by-layer Assembled Polymer/MOF Membrane for H2/CO2 Separation
Material Characterization Testing of Synthetic Granular Composites Used in Equine Sports Surfaces
Microporous Copper Spheres: Processing, Morphology, and Application
New Strategies for Defects Formation and Amorphization of Metal-organic Frameworks
P2-30: ScSZ-MC Dual-phase Tubular Membrane for Pre-combustion CO2 Capture
P2-31: Geopolymer Adsorbents for Harvesting N and P from Poultry Litter
Porous Organic Polymer-based Nanotraps for Water Purification
Probing the Mechanisms of Reactive Capture and Conversion of CO2 into Inorganic Carbonates Using Architected Calcium and Magnesium Silicates
Recent Advances in High Temperature Multiphase Solid/Molten Carbonate Membranes for CO2 Capture and Conversion
Selected Pillared Cyanonickelate Based Metal Organic Frameworks (MOFs) for CO2 Capture Applications
Small Molecules as Guests in Metal-organic Frameworks
Structure and CO2 Adsorption Sites in the Flexible Coordination Polymer Ni-Dbm-Bpy from DFT
Thermodynamics of Molybdenum Oxide Clusters Encapsulated in Zeolite Y

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